Radical reaction control in the AdoMet radical enzyme CDG Synthase (QueE): consolidate, destabilize, accelerate

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Radical reaction control in the AdoMet radical enzyme CDG Synthase (QueE): consolidate, destabilize, accelerate

Controlling radical intermediates and thus catalysing and directing complex radical reactions is a central feature of S-adensosylmethionine (SAM)-dependent radical enzymes. We report ab initio and DFT calculations highlighting the specific influence of ion complexation, including Mg2+, identified as...

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Bibliographic Details
Main Authors:	Jäger, Christof M., Croft, Anna K.
Format:	Article
Published:	Wiley-VCH Verlag 2017
Subjects:	Catalysis Radical SAM enzymes Radical stabilization energies Computational chemistry Radical clocks
Online Access:	https://eprints.nottingham.ac.uk/39964/

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