Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes

QR Code

Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes

Determining the electronic structure of actinide complexes is intrinsically challenging because inter-electronic repulsion, crystal field, and spin–orbit coupling effects can be of similar magnitude. Moreover, such efforts have been hampered by the lack of structurally analogous families of complexe...

Full description

Bibliographic Details
Main Authors:	King, David M., Cleaves, Peter A., Wooles, Ashley J., Gardner, Benedict. M., Chilton, Nicholas F., Tuna, Floriana, Lewis, William, McInnes, Eric J.L., Liddle, Stephen T.
Format:	Article
Published:	Nature Publishing Group 2016
Online Access:	https://eprints.nottingham.ac.uk/39893/

Similar Items

Two-electron reductive carbonylation of terminal uranium(V) and uranium(VI) nitrides to cyanate by carbon monoxide
by: Cleaves, Peter A., et al.
Published: (2014)

Terminal uranium(V/VI) nitride activation of carbon dioxide and carbon disulfide: factors governing diverse and well-defined cleavage and redox reactions
by: Cleaves, Peter A., et al.
Published: (2017)

Synthesis and characterization of an f‑block terminal parent imido [U=NH] complex: a masked uranium(IV) nitride
by: King, David M., et al.
Published: (2014)

Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes
by: Gardner, Benedict M., et al.
Published: (2014)

Synthesis, reactivity, and electronic structure of molecular uranium nitrides
by: Cleaves, Peter A.
Published: (2016)

Synthesis, characterization, and reactivity of a uranium(VI) carbene imido oxo complex
by: Lu, Erli, et al.
Published: (2014)

Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR′ Units (R=Ph2PNSiMe3; R′=CPh3): Alkali-Metal-Mediated push–pull effects with an Amido Auxiliary
by: Lu, Erli, et al.
Published: (2016)

Emergence of comparable covalency in isostructural cerium(IV)- and uranium(IV)-carbon multiple bonds
by: Gregson, Matthew, et al.
Published: (2016)

Isolation of elusive HAsAsH in a crystalline diuranium(IV) complex
by: Gardner, Benedict M., et al.
Published: (2015)

An inverted-sandwich diuranium μ-η5:η5-cyclo-P5 complex supported by U-P5 δ-bonding
by: Gardner, Benedict M., et al.
Published: (2015)

The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium(iv) and uranium(iv) alkyls
by: Gardner, Benedict M., et al.
Published: (2014)

A monometallic lanthanide bis(methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour
by: Gregson, Matthew, et al.
Published: (2015)

Uranium Series Dating
by: Zhao, J., et al.
Published: (2011)

Alkali metal derivatives of an ortho-phenylene diamine
by: Robinson, Sarah, et al.
Published: (2013)

The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
by: Gregson, Matthew, et al.
Published: (2017)

Dissolved Organic Carbon Reduces Uranium Bioavailability and Toxicity. 1. Characterization of an quatic Fulvic Acid and Its Complexation with Uranium[VI]
by: Trenfield, M., et al.
Published: (2011)

Density functional study of manganese atom adsorption on hydrogen-terminated armchair boron nitride nanoribbons
by: Abdullahi, Yusuf Zuntu, et al.
Published: (2014)

Lability and solubility of uranium and thorium in soil
by: Ahmed, Hayam Mohamed Mahmoud
Published: (2014)

Uranium–lead, extraterrestrial, planetary materials
by: Nemchin, Alexander
Published: (2015)

The Uranium Trade in the Indian Ocean Region
by: Rumley, Dennis, et al.
Published: (2008)

Characterization of uranium redox state in organic-rich Eocene sediments
by: Cumberland, S., et al.
Published: (2018)

Buoffant cap
by: Hamzah, Hayati, et al.
Published: (2020)

Bump cap
by: Rosaidi, Najwa Qisteena, et al.
Published: (2020)

Power Plays. Enriched Uranium and Homeland Security
by: Hubbard, Chris
Published: (2010)

Retention of uranium in complexly altered zircon: An example from Bancroft, Ontario
by: Nasdala, L., et al.
Published: (2009)

NanoCap: A framework for generating capped carbon nanotubes and fullerenes
by: Robinson, Marc, et al.
Published: (2014)

Carbon nitride photocatalysts
by: Zhang, J., et al.
Published: (2018)

The Impact of the Credit Rating on Capital Structure in UK Large-cap and Small-cap Firms
by: Zhou, Weiwei
Published: (2019)

Solvent extraction reaction of uranium (VI) sulfate with Alamine 336
by: Avelar, Erica, et al.
Published: (2014)

Hydrometallurgical removal of uranium and thorium from Ethiopian tantalite ore
by: Cheru, M., et al.
Published: (2018)

Enhanced diffusion of Uranium and Thorium linked to crystal plasticity in zircon
by: Timms, Nicholas Eric, et al.
Published: (2006)

Uranium exports and non-proliferation: A policy coordination challenge
by: Hubbard, Christopher
Published: (2007)

Radiolytic alteration of biopolymers in the Mulga Rock (Australia) uranium deposit
by: Jaraula, Caroline, et al.
Published: (2014)

Uranium mobility in organic matter-rich sediments: A review of geological and geochemical processes
by: Grice, Kliti, et al.
Published: (2016)

Another feather in MMMC's cap
Published: (2010)

KPT-CAP tangani pengangguran
by: Harian Metro
Published: (2020)

Terminal tectono-magmatic phase of the New England Orogen driven by lithospheric delamination
by: Olierook, Hugo, et al.
Published: (2022)

The determinants of Capital Structure: a comparison between small-cap and large-cap US firms
by: Gembali, Ravi Raj
Published: (2018)

Students' perceptions of Classroom Assessment Practices (CAPs) and its relationship among the six CAPs scales

Natural uranium and thorium isotopes in sediment cores off Malaysian ports
by: Yusoff, Abdul Hafidz, et al.
Published: (2015)