An efficient synthesis of substituted chrysenes
Substituted chrysenes have been swiftly synthesised by the 6-endo-dig cyclisation of ethynylnaphthalenes using platinum(II) chloride. Cyclisation precursors were directly prepared from commercially available 2-bromoaldehydes in a telescoped synthetic procedure involving a Cannizzaro triggered cascad...
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| Format: | Article |
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Elsevier
2017
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| Online Access: | https://eprints.nottingham.ac.uk/39306/ |
| _version_ | 1848795806339956736 |
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| author | Eccleshare, Lee Selzer, Sean Woodward, Simon |
| author_facet | Eccleshare, Lee Selzer, Sean Woodward, Simon |
| author_sort | Eccleshare, Lee |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Substituted chrysenes have been swiftly synthesised by the 6-endo-dig cyclisation of ethynylnaphthalenes using platinum(II) chloride. Cyclisation precursors were directly prepared from commercially available 2-bromoaldehydes in a telescoped synthetic procedure involving a Cannizzaro triggered cascade and subsequent dehydration and desilylation. This short synthetic procedure allows rapid access to derivatives of biologically active molecules with useful electronic properties. |
| first_indexed | 2025-11-14T19:37:56Z |
| format | Article |
| id | nottingham-39306 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:37:56Z |
| publishDate | 2017 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-393062020-05-04T18:28:09Z https://eprints.nottingham.ac.uk/39306/ An efficient synthesis of substituted chrysenes Eccleshare, Lee Selzer, Sean Woodward, Simon Substituted chrysenes have been swiftly synthesised by the 6-endo-dig cyclisation of ethynylnaphthalenes using platinum(II) chloride. Cyclisation precursors were directly prepared from commercially available 2-bromoaldehydes in a telescoped synthetic procedure involving a Cannizzaro triggered cascade and subsequent dehydration and desilylation. This short synthetic procedure allows rapid access to derivatives of biologically active molecules with useful electronic properties. Elsevier 2017-02-01 Article PeerReviewed Eccleshare, Lee, Selzer, Sean and Woodward, Simon (2017) An efficient synthesis of substituted chrysenes. Tetrahedron, 58 (5). pp. 393-395. ISSN 0040-4020 Polyaromatic hydrocarbon; Carbocyclisation; Microwave-assisted synthesis http://www.sciencedirect.com/science/article/pii/S0040403916316306 doi:10.1016/j.tetlet.2016.12.004 doi:10.1016/j.tetlet.2016.12.004 |
| spellingShingle | Polyaromatic hydrocarbon; Carbocyclisation; Microwave-assisted synthesis Eccleshare, Lee Selzer, Sean Woodward, Simon An efficient synthesis of substituted chrysenes |
| title | An efficient synthesis of substituted chrysenes |
| title_full | An efficient synthesis of substituted chrysenes |
| title_fullStr | An efficient synthesis of substituted chrysenes |
| title_full_unstemmed | An efficient synthesis of substituted chrysenes |
| title_short | An efficient synthesis of substituted chrysenes |
| title_sort | efficient synthesis of substituted chrysenes |
| topic | Polyaromatic hydrocarbon; Carbocyclisation; Microwave-assisted synthesis |
| url | https://eprints.nottingham.ac.uk/39306/ https://eprints.nottingham.ac.uk/39306/ https://eprints.nottingham.ac.uk/39306/ |