The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene
Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Published: |
Royal Society of Chemistry
2016
|
| Online Access: | https://eprints.nottingham.ac.uk/38947/ |
| _version_ | 1848795726477262848 |
|---|---|
| author | Martin, Adam D. Easun, Timothy L. Argent, Stephen P. Lewis, William Blake, Alexander J. Schröder, Martin |
| author_facet | Martin, Adam D. Easun, Timothy L. Argent, Stephen P. Lewis, William Blake, Alexander J. Schröder, Martin |
| author_sort | Martin, Adam D. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2. |
| first_indexed | 2025-11-14T19:36:40Z |
| format | Article |
| id | nottingham-38947 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:36:40Z |
| publishDate | 2016 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-389472020-05-04T18:20:50Z https://eprints.nottingham.ac.uk/38947/ The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene Martin, Adam D. Easun, Timothy L. Argent, Stephen P. Lewis, William Blake, Alexander J. Schröder, Martin Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2. Royal Society of Chemistry 2016-11-16 Article PeerReviewed Martin, Adam D., Easun, Timothy L., Argent, Stephen P., Lewis, William, Blake, Alexander J. and Schröder, Martin (2016) The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. CrystEngComm, 19 . pp. 603-607. ISSN 1466-8033 http://pubs.rsc.org/en/Content/ArticleLanding/2017/CE/C6CE01965J#!divAbstract doi:10.1039/C6CE01965J doi:10.1039/C6CE01965J |
| spellingShingle | Martin, Adam D. Easun, Timothy L. Argent, Stephen P. Lewis, William Blake, Alexander J. Schröder, Martin The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| title | The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| title_full | The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| title_fullStr | The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| title_full_unstemmed | The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| title_short | The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| title_sort | effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene |
| url | https://eprints.nottingham.ac.uk/38947/ https://eprints.nottingham.ac.uk/38947/ https://eprints.nottingham.ac.uk/38947/ |