The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila

Samples of non-mature and añejo (matured) tequila of the same brand/provenance were analysed using GC–MS and gas chromatography olfactometry (GC-O)/aroma extract dilution analysis (AEDA) to provide quantitative data on the most odour active compounds that contribute to the aroma of these spirits. Ex...

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Main Authors: González-Robles, Ivonne Wendolyne, Cook, David J.
Format: Article
Published: Wiley 2016
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Online Access:https://eprints.nottingham.ac.uk/38501/
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author González-Robles, Ivonne Wendolyne
Cook, David J.
author_facet González-Robles, Ivonne Wendolyne
Cook, David J.
author_sort González-Robles, Ivonne Wendolyne
building Nottingham Research Data Repository
collection Online Access
description Samples of non-mature and añejo (matured) tequila of the same brand/provenance were analysed using GC–MS and gas chromatography olfactometry (GC-O)/aroma extract dilution analysis (AEDA) to provide quantitative data on the most odour active compounds that contribute to the aroma of these spirits. Extracts of non-mature tequila were characterized by 26 odour-active regions, which included ethyl hexanoate, ethyl octanoate, 2-phenylethyl acetate, β-damascenone, isoamyl alcohol and octanoic acid as the most odour-active compounds (flavour dilution, FD, factor ≥ 6561). In contrast, extracts of the mature spirit showed 36 odour-active zones, where the compounds with the highest FD factors (6561) were ethyl hexanoate, ethyl octanoate, 2-phenylethyl acetate, isoamyl alcohol, phenethyl alcohol, guaiacol, 4-ethyl guaiacol, vanillin, cis/trans whisky lactones, β-damascenone and octanoic acid. The aromagram of mature tequila was thus differentiated from that of the non-mature spirit owing to the presence of cask-extractive compounds and the increased FD factors of certain terpenes, higher alcohols and acetals. This study provides a comprehensive and quantitative understanding of changes in key odourants of tequila as a result of the maturation process and also reveals a further characterization of the likely impact of each compound on overall spirit flavour, in terms of odour activity values.
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spelling nottingham-385012020-05-04T18:00:37Z https://eprints.nottingham.ac.uk/38501/ The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila González-Robles, Ivonne Wendolyne Cook, David J. Samples of non-mature and añejo (matured) tequila of the same brand/provenance were analysed using GC–MS and gas chromatography olfactometry (GC-O)/aroma extract dilution analysis (AEDA) to provide quantitative data on the most odour active compounds that contribute to the aroma of these spirits. Extracts of non-mature tequila were characterized by 26 odour-active regions, which included ethyl hexanoate, ethyl octanoate, 2-phenylethyl acetate, β-damascenone, isoamyl alcohol and octanoic acid as the most odour-active compounds (flavour dilution, FD, factor ≥ 6561). In contrast, extracts of the mature spirit showed 36 odour-active zones, where the compounds with the highest FD factors (6561) were ethyl hexanoate, ethyl octanoate, 2-phenylethyl acetate, isoamyl alcohol, phenethyl alcohol, guaiacol, 4-ethyl guaiacol, vanillin, cis/trans whisky lactones, β-damascenone and octanoic acid. The aromagram of mature tequila was thus differentiated from that of the non-mature spirit owing to the presence of cask-extractive compounds and the increased FD factors of certain terpenes, higher alcohols and acetals. This study provides a comprehensive and quantitative understanding of changes in key odourants of tequila as a result of the maturation process and also reveals a further characterization of the likely impact of each compound on overall spirit flavour, in terms of odour activity values. Wiley 2016-07-19 Article PeerReviewed González-Robles, Ivonne Wendolyne and Cook, David J. (2016) The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila. Journal of the Insitute of Brewing, 122 (3). pp. 369-380. ISSN 2050-0416 Agave tequilana; Volatile compounds; Aroma extract dilution analysis: Gas 22 chromatography Mass spectrometry; Tequila; Non-mature; Mature. http://dx.doi.org/10.1002/jib.333 doi:10.1002/jib.333 doi:10.1002/jib.333
spellingShingle Agave tequilana; Volatile compounds; Aroma extract dilution analysis: Gas 22 chromatography
Mass spectrometry; Tequila; Non-mature; Mature.
González-Robles, Ivonne Wendolyne
Cook, David J.
The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
title The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
title_full The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
title_fullStr The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
title_full_unstemmed The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
title_short The impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
title_sort impact of maturation on concentrations of key odour active compounds which determine the aroma of tequila
topic Agave tequilana; Volatile compounds; Aroma extract dilution analysis: Gas 22 chromatography
Mass spectrometry; Tequila; Non-mature; Mature.
url https://eprints.nottingham.ac.uk/38501/
https://eprints.nottingham.ac.uk/38501/
https://eprints.nottingham.ac.uk/38501/