Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF
Molecules of tris(2,2’-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramolecular capsular structure in the solid state. Three BEDT-TTF residues from one complex lie in the three grooves between coordinated bipyridine...
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| Format: | Article |
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American Chemical Society
2016
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| Online Access: | https://eprints.nottingham.ac.uk/37760/ |
| _version_ | 1848795527247822848 |
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| author | Wang, Qiang Martin, Lee Blake, Alexander J. Day, Peter Akutsu, Hiroki Wallis, John D. |
| author_facet | Wang, Qiang Martin, Lee Blake, Alexander J. Day, Peter Akutsu, Hiroki Wallis, John D. |
| author_sort | Wang, Qiang |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Molecules of tris(2,2’-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramolecular capsular structure in the solid state. Three BEDT-TTF residues from one complex lie in the three grooves between coordinated bipyridines of the other complex, and vice versa, to form a capsule with three-fold rotational symmetry and an internal volume of ca. 160 Å3. Further aspects of the coordination chemistry of this ligand, its 6-substituted isomer and the 2,2’:6’2’’- terpyridyl-4’-thiomethyl-BEDT-TTF analogue are described. |
| first_indexed | 2025-11-14T19:33:30Z |
| format | Article |
| id | nottingham-37760 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:33:30Z |
| publishDate | 2016 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-377602020-05-04T18:13:36Z https://eprints.nottingham.ac.uk/37760/ Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF Wang, Qiang Martin, Lee Blake, Alexander J. Day, Peter Akutsu, Hiroki Wallis, John D. Molecules of tris(2,2’-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramolecular capsular structure in the solid state. Three BEDT-TTF residues from one complex lie in the three grooves between coordinated bipyridines of the other complex, and vice versa, to form a capsule with three-fold rotational symmetry and an internal volume of ca. 160 Å3. Further aspects of the coordination chemistry of this ligand, its 6-substituted isomer and the 2,2’:6’2’’- terpyridyl-4’-thiomethyl-BEDT-TTF analogue are described. American Chemical Society 2016-09-06 Article PeerReviewed Wang, Qiang, Martin, Lee, Blake, Alexander J., Day, Peter, Akutsu, Hiroki and Wallis, John D. (2016) Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF. Inorganic Chemistry, 55 (17). pp. 8543-8551. ISSN 1520-510X http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b01101 doi:10.1021/acs.inorgchem.6b01101 doi:10.1021/acs.inorgchem.6b01101 |
| spellingShingle | Wang, Qiang Martin, Lee Blake, Alexander J. Day, Peter Akutsu, Hiroki Wallis, John D. Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF |
| title | Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF |
| title_full | Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF |
| title_fullStr | Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF |
| title_full_unstemmed | Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF |
| title_short | Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF |
| title_sort | coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted bedt-ttfs: formation of a supramolecular capsule motif by the iron(ii) tris complex of 2,2’-bipyridine-4-thiomethyl-bedt-ttf |
| url | https://eprints.nottingham.ac.uk/37760/ https://eprints.nottingham.ac.uk/37760/ https://eprints.nottingham.ac.uk/37760/ |