Asymmetric pentafulvene carbometalation-access to enantiopure titanocene dichlorides of biological relevance

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Asymmetric pentafulvene carbometalation-access to enantiopure titanocene dichlorides of biological relevance

Unprecedented asymmetric copper-catalyzed addition of ZnEt2 (ZnBu2) to the exocyclic C[DOUBLE BOND]C bond of pentafulvenes C5H4([DOUBLE BOND]CHAr) (Ar=2-MeOPh and related species) results in enantiomerically enriched (up to 93:7 e.r.) cyclopentadienyl ligands (C5H4CHEtAr; abbreviated CpR). Copper ca...

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Bibliographic Details
Main Authors:	Cini, Melchior, Bradshaw, Tracey D., Woodward, Simon, Lewis, William
Format:	Article
Published:	Wiley 2015
Online Access:	https://eprints.nottingham.ac.uk/37572/

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