Gelation properties of self-assembling N-acyl modified cytidine derivatives

In this study we report the synthesis of new cytidine derived gelators possessing acyl chains of different lengths. These low molecular weight gelators were shown to form self-supporting gels at 0.5 % (w/v) in binary systems of aqueous miscible polar organic solvent and water. The representative gel...

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Main Authors: Skilling, Kathryn J., Ndungu, A., Kellam, Barrie, Ashford, M., Bradshaw, Tracey D., Marlow, Maria
Format: Article
Published: Royal Society of Chemistry 2014
Online Access:https://eprints.nottingham.ac.uk/37331/
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author Skilling, Kathryn J.
Ndungu, A.
Kellam, Barrie
Ashford, M.
Bradshaw, Tracey D.
Marlow, Maria
author_facet Skilling, Kathryn J.
Ndungu, A.
Kellam, Barrie
Ashford, M.
Bradshaw, Tracey D.
Marlow, Maria
author_sort Skilling, Kathryn J.
building Nottingham Research Data Repository
collection Online Access
description In this study we report the synthesis of new cytidine derived gelators possessing acyl chains of different lengths. These low molecular weight gelators were shown to form self-supporting gels at 0.5 % (w/v) in binary systems of aqueous miscible polar organic solvent and water. The representative gels were studied using rheology and their fibrillar structure confirmed by TEM imaging and FTIR. We further demonstrated the use of these gels as potential drug delivery platforms by monitoring release characteristics of both high and low molecular weight fluorescently labelled tracers.
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publishDate 2014
publisher Royal Society of Chemistry
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spelling nottingham-373312020-05-04T16:55:19Z https://eprints.nottingham.ac.uk/37331/ Gelation properties of self-assembling N-acyl modified cytidine derivatives Skilling, Kathryn J. Ndungu, A. Kellam, Barrie Ashford, M. Bradshaw, Tracey D. Marlow, Maria In this study we report the synthesis of new cytidine derived gelators possessing acyl chains of different lengths. These low molecular weight gelators were shown to form self-supporting gels at 0.5 % (w/v) in binary systems of aqueous miscible polar organic solvent and water. The representative gels were studied using rheology and their fibrillar structure confirmed by TEM imaging and FTIR. We further demonstrated the use of these gels as potential drug delivery platforms by monitoring release characteristics of both high and low molecular weight fluorescently labelled tracers. Royal Society of Chemistry 2014-10-22 Article PeerReviewed Skilling, Kathryn J., Ndungu, A., Kellam, Barrie, Ashford, M., Bradshaw, Tracey D. and Marlow, Maria (2014) Gelation properties of self-assembling N-acyl modified cytidine derivatives. Journal of Materials Chemistry B, 2 (47). pp. 8412-8417. ISSN 2050-750X http://pubs.rsc.org/en/Content/ArticleLanding/2014/TB/C4TB01375A#!divAbstract doi:10.1039/C4TB01375A doi:10.1039/C4TB01375A
spellingShingle Skilling, Kathryn J.
Ndungu, A.
Kellam, Barrie
Ashford, M.
Bradshaw, Tracey D.
Marlow, Maria
Gelation properties of self-assembling N-acyl modified cytidine derivatives
title Gelation properties of self-assembling N-acyl modified cytidine derivatives
title_full Gelation properties of self-assembling N-acyl modified cytidine derivatives
title_fullStr Gelation properties of self-assembling N-acyl modified cytidine derivatives
title_full_unstemmed Gelation properties of self-assembling N-acyl modified cytidine derivatives
title_short Gelation properties of self-assembling N-acyl modified cytidine derivatives
title_sort gelation properties of self-assembling n-acyl modified cytidine derivatives
url https://eprints.nottingham.ac.uk/37331/
https://eprints.nottingham.ac.uk/37331/
https://eprints.nottingham.ac.uk/37331/