Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism

For the prototype diluted ferromagnetic semiconductor (Ga,Mn)As, there is a fundamental concern about the electronic states near the Fermi level, i.e., whether the Fermi level resides in a well-separated impurity band derived from Mn doping (impurity-band model) or in the valence band that is alread...

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Main Authors: Zhou, Shengqiang, Li, Lin, Yuan, Ye, Rushforth, A.W., Chen, Lin, Wang, Yutian, Böttger, R., Heller, R., Zhao, Jianhua, Edmonds, K.W., Campion, R.P., Gallagher, B.L., Timm, C., Helm, M.
Format: Article
Published: American Physical Society 2016
Online Access:https://eprints.nottingham.ac.uk/37051/
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author Zhou, Shengqiang
Li, Lin
Yuan, Ye
Rushforth, A.W.
Chen, Lin
Wang, Yutian
Böttger, R.
Heller, R.
Zhao, Jianhua
Edmonds, K.W.
Campion, R.P.
Gallagher, B.L.
Timm, C.
Helm, M.
author_facet Zhou, Shengqiang
Li, Lin
Yuan, Ye
Rushforth, A.W.
Chen, Lin
Wang, Yutian
Böttger, R.
Heller, R.
Zhao, Jianhua
Edmonds, K.W.
Campion, R.P.
Gallagher, B.L.
Timm, C.
Helm, M.
author_sort Zhou, Shengqiang
building Nottingham Research Data Repository
collection Online Access
description For the prototype diluted ferromagnetic semiconductor (Ga,Mn)As, there is a fundamental concern about the electronic states near the Fermi level, i.e., whether the Fermi level resides in a well-separated impurity band derived from Mn doping (impurity-band model) or in the valence band that is already merged with the Mn-derived impurity band (valence-band model). We investigate this question by carefully shifting the Fermi level by means of carrier compensation. We use helium-ion implantation, a standard industry technology, to precisely compensate the hole doping of GaAs-based diluted ferromagnetic semiconductors while keeping the Mn concentration constant. We monitor the change of Curie temperature (TC) and conductivity. For a broad range of samples including (Ga,Mn)As and (Ga,Mn)(As,P) with various Mn and P concentrations, we observe a smooth decrease of TC with carrier compensation over a wide temperature range while the conduction is changed from metallic to insulating. The existence of TC below 10 K is also confirmed in heavily compensated samples. Our experimental results are naturally explained within the valence-band picture.
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publishDate 2016
publisher American Physical Society
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spelling nottingham-370512020-05-04T18:07:02Z https://eprints.nottingham.ac.uk/37051/ Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism Zhou, Shengqiang Li, Lin Yuan, Ye Rushforth, A.W. Chen, Lin Wang, Yutian Böttger, R. Heller, R. Zhao, Jianhua Edmonds, K.W. Campion, R.P. Gallagher, B.L. Timm, C. Helm, M. For the prototype diluted ferromagnetic semiconductor (Ga,Mn)As, there is a fundamental concern about the electronic states near the Fermi level, i.e., whether the Fermi level resides in a well-separated impurity band derived from Mn doping (impurity-band model) or in the valence band that is already merged with the Mn-derived impurity band (valence-band model). We investigate this question by carefully shifting the Fermi level by means of carrier compensation. We use helium-ion implantation, a standard industry technology, to precisely compensate the hole doping of GaAs-based diluted ferromagnetic semiconductors while keeping the Mn concentration constant. We monitor the change of Curie temperature (TC) and conductivity. For a broad range of samples including (Ga,Mn)As and (Ga,Mn)(As,P) with various Mn and P concentrations, we observe a smooth decrease of TC with carrier compensation over a wide temperature range while the conduction is changed from metallic to insulating. The existence of TC below 10 K is also confirmed in heavily compensated samples. Our experimental results are naturally explained within the valence-band picture. American Physical Society 2016-08-15 Article PeerReviewed Zhou, Shengqiang, Li, Lin, Yuan, Ye, Rushforth, A.W., Chen, Lin, Wang, Yutian, Böttger, R., Heller, R., Zhao, Jianhua, Edmonds, K.W., Campion, R.P., Gallagher, B.L., Timm, C. and Helm, M. (2016) Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism. Physical Review B, 94 (7). 075205-1. ISSN 2469-9969 http://journals.aps.org/prb/abstract/10.1103/PhysRevB.94.075205 doi:10.1103/PhysRevB.94.075205 doi:10.1103/PhysRevB.94.075205
spellingShingle Zhou, Shengqiang
Li, Lin
Yuan, Ye
Rushforth, A.W.
Chen, Lin
Wang, Yutian
Böttger, R.
Heller, R.
Zhao, Jianhua
Edmonds, K.W.
Campion, R.P.
Gallagher, B.L.
Timm, C.
Helm, M.
Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism
title Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism
title_full Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism
title_fullStr Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism
title_full_unstemmed Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism
title_short Precise tuning of the Curie temperature of (Ga,Mn)As-based magnetic semiconductors by hole compensation: Support for valence-band ferromagnetism
title_sort precise tuning of the curie temperature of (ga,mn)as-based magnetic semiconductors by hole compensation: support for valence-band ferromagnetism
url https://eprints.nottingham.ac.uk/37051/
https://eprints.nottingham.ac.uk/37051/
https://eprints.nottingham.ac.uk/37051/