Development of a redox-free mitsunobu reaction exploiting phosphine oxides as precursors to dioxyphosphoranes
The development of the first redox-free protocol for the Mitsunobu reaction is described. This has been achieved by exploiting triphenylphosphine oxide – the unwanted by-product in the conventional Mitsunobu reaction – as the precursor to the active P(V) coupling reagent. Multinuclear NMR studies ar...
| Main Authors: | Tang, Xiaoping, Chapman, Charlotte, Whiting, Matthew, Denton, Ross Matthew |
|---|---|
| Format: | Article |
| Published: |
Royal Society of Chemistry
2014
|
| Online Access: | https://eprints.nottingham.ac.uk/35947/ |
Similar Items
New directions in the Mitsunobu reaction
by: Beddoe, Rhydian
Published: (2021)
by: Beddoe, Rhydian
Published: (2021)
Studies towards a phosphorus(V)-catalysed Mitsunobu reaction
by: Shannon-Little, Andrew Laurence
Published: (2016)
by: Shannon-Little, Andrew Laurence
Published: (2016)
Design, synthesis and applications of hydroxylmethyl-aryl phosphine oxides in phosphorus catalysis
by: Chapman, Charlotte Grace
Published: (2015)
by: Chapman, Charlotte Grace
Published: (2015)
Reaction paths of phosphine dissociation on silicon (001)
by: Warschkow, O., et al.
Published: (2016)
by: Warschkow, O., et al.
Published: (2016)
Atomic-scale observation and control of the reaction of phosphine with silicon
by: Schofield, S., et al.
Published: (2006)
by: Schofield, S., et al.
Published: (2006)
Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation
by: Fearnley, A.F., et al.
Published: (2016)
by: Fearnley, A.F., et al.
Published: (2016)
A practical and catalyst-free trifluoroethylation reaction of amines using trifluoroacetic acid
by: Andrews, Keith G., et al.
Published: (2017)
by: Andrews, Keith G., et al.
Published: (2017)
Synthesis of Benzofuroquinolines via Phosphine-Free Direct Arylation of 4-Phenoxyquinolines in Air
by: Shanahan, R., et al.
Published: (2018)
by: Shanahan, R., et al.
Published: (2018)
The solvent extraction behaviour of chromium with Bis (2,4,4-trimethylpentyl) phosphinic acid (Cyanex [R] 272)
by: Lanagan, Matthew D.
Published: (2003)
by: Lanagan, Matthew D.
Published: (2003)
Nuclear weapons and intergenerational exploitation
by: Rendall, Matthew
Published: (2007)
by: Rendall, Matthew
Published: (2007)
Non-identity, sufficiency and exploitation
by: Rendall, Matthew
Published: (2011)
by: Rendall, Matthew
Published: (2011)
The nucleophilic, phosphine-catalyzed thiol-ene click reaction and convergent star synthesis with RAFT-prepared homopolymers
by: Chan, J., et al.
Published: (2009)
by: Chan, J., et al.
Published: (2009)
Sequential phosphine-catalyzed, nucleophilic thiol ene/radical-mediated thiol-yne reactions and the facile orthogonal synthesis of polyfunctional materials
by: Chan, J., et al.
Published: (2009)
by: Chan, J., et al.
Published: (2009)
Phosphine Dissociation and Diffusion on Si(001) Observed at the Atomic Scale
by: Schofield, S., et al.
Published: (2006)
by: Schofield, S., et al.
Published: (2006)
Single-source precursor deposition of low-toxicity sulphides for thin film photovoltaic devices
by: Bishop, Matthew T.
Published: (2019)
by: Bishop, Matthew T.
Published: (2019)
Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten-iridium clusters
by: Simpson, Peter, et al.
Published: (2015)
by: Simpson, Peter, et al.
Published: (2015)
Asymmetric transition metal-catalyzed alkyl addition to imines with chiral phosphine ligands
by: El Hajjaji, Samir
Published: (2010)
by: El Hajjaji, Samir
Published: (2010)
Water Content and Water Evolution from Reaction-Bonded Aluminum Oxide (RBAO) Powder Precursors.
by: Jadambaa, Temuujin, et al.
Published: (2008)
by: Jadambaa, Temuujin, et al.
Published: (2008)
On the fabrication and characteristics of PAN precursor fiber in the solvent-free coagulation process
by: Ismail, Ahmad Fauzi, et al.
Published: (2006)
by: Ismail, Ahmad Fauzi, et al.
Published: (2006)
Metal-Free Carbocatalysis in Advanced Oxidation Reactions
by: Duan, Xiaoguang, et al.
Published: (2018)
by: Duan, Xiaoguang, et al.
Published: (2018)
Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)
by: Henderson, William, et al.
Published: (2018)
by: Henderson, William, et al.
Published: (2018)
Evaluation of the Predict-Observe-Explain Instructional Strategy to Enhance Students’ Understanding of redox reactions
by: Treagust, David, et al.
Published: (2014)
by: Treagust, David, et al.
Published: (2014)
Effect of reaction temperature and flow rate of precursor on formation of multi-walled carbon nanotubes
by: Tee, Jia Chee, et al.
Published: (2008)
by: Tee, Jia Chee, et al.
Published: (2008)
Synthesis, Characterization And
Structural Studies Of Palladium(Ii)
Complexes With Some Substituted
Phosphine And Arsine Ligands
by: Mohidin Yahya, Hamdya Farhana
Published: (2018)
by: Mohidin Yahya, Hamdya Farhana
Published: (2018)
Synthesis and characterization of novel organometallic chromium hexacarbonyl derivatives via ligand (L) substitution, where L = tris (3-methylphenyl) arsine, tris (M-fluorophenyl) phosphine and tris [3, 5-Bis (trifluoromethyl) phenyl] phosphine
by: Muhammad Yazid, Mohamad Yunus
Published: (2012)
by: Muhammad Yazid, Mohamad Yunus
Published: (2012)
Synthesis of malhamensilipin A exploiting iterative epoxidation/chlorination: experimental and computational analysis of epoxide-derived chloronium ions
by: Saska, J., et al.
Published: (2016)
by: Saska, J., et al.
Published: (2016)
An analysis of the visual representation of redox reactions in secondary chemistry textbooks from different Chinese communities
by: Chen, X., et al.
Published: (2019)
by: Chen, X., et al.
Published: (2019)
The control of sclerotinia stem rot on oilseed rape (Brassica napus): current practices and future opportunities
by: Derbyshire, Mark, et al.
Published: (2016)
by: Derbyshire, Mark, et al.
Published: (2016)
Catalytic reductive N-alkylation of amines using carboxylic acids
by: Andrews, Keith Gordon, et al.
Published: (2015)
by: Andrews, Keith Gordon, et al.
Published: (2015)
Text analysis on early reactions to ChatGPT as a tool for academic progress or exploitation
by: Bukar, Umar Ali, et al.
Published: (2024)
by: Bukar, Umar Ali, et al.
Published: (2024)
Redox equilibria of iron oxides in aqueous-based magnetite dispersions:Effect of pH and redox potential
by: Pang, S.C., et al.
Published: (2007)
by: Pang, S.C., et al.
Published: (2007)
Redox decoupling and redox budgets: Conceptual tools for thestudy of earth systems
by: Evans, Katy
Published: (2006)
by: Evans, Katy
Published: (2006)
Redox behavior of supported Pd particles and its effect on oxygen reduction reaction in intermediate temperature solid oxide fuel cells
by: Liang, F., et al.
Published: (2011)
by: Liang, F., et al.
Published: (2011)
Redox electrolytes in supercapacitors
by: Akinwolemiwa, Bamidele, et al.
Published: (2015)
by: Akinwolemiwa, Bamidele, et al.
Published: (2015)
Synergistic catalyst-support interactions in a graphene-Mn3O4 electrocatalyst for vanadium redox flow batteries
by: Ejigu, Andinet, et al.
Published: (2015)
by: Ejigu, Andinet, et al.
Published: (2015)
Variational Solutions in Orbital Free Density Functional Theory
by: Ryley, Matthew S
Published: (2020)
by: Ryley, Matthew S
Published: (2020)
Is the free market acceptable to everyone?
by: Clayton, Matthew, et al.
Published: (2015)
by: Clayton, Matthew, et al.
Published: (2015)
Synthesis And Characterisation Of New Ru3 AND Os3 Clusters With Sulphur Containing Phosphines, Alkyne, And Antimony Ligands
by: Abdelnasir, Hafiz Malik Hussien
Published: (2017)
by: Abdelnasir, Hafiz Malik Hussien
Published: (2017)
Exploitation and surplus
by: O'Hara, Phillip
Published: (2008)
by: O'Hara, Phillip
Published: (2008)
Redox electrode materials for supercapatteries
by: Yu, Linpo, et al.
Published: (2016)
by: Yu, Linpo, et al.
Published: (2016)
Similar Items
-
New directions in the Mitsunobu reaction
by: Beddoe, Rhydian
Published: (2021) -
Studies towards a phosphorus(V)-catalysed Mitsunobu reaction
by: Shannon-Little, Andrew Laurence
Published: (2016) -
Design, synthesis and applications of hydroxylmethyl-aryl phosphine oxides in phosphorus catalysis
by: Chapman, Charlotte Grace
Published: (2015) -
Reaction paths of phosphine dissociation on silicon (001)
by: Warschkow, O., et al.
Published: (2016) -
Atomic-scale observation and control of the reaction of phosphine with silicon
by: Schofield, S., et al.
Published: (2006)