Synthesis and characterization of an f‑block terminal parent imido [U=NH] complex: a masked uranium(IV) nitride

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Synthesis and characterization of an f‑block terminal parent imido [U=NH] complex: a masked uranium(IV) nitride

Deprotonation of [U(TrenTIPS)(NH2)] (1) [TrenTIPS = N(CH2CH2NSiPri3)3] with organoalkali metal reagents MR (M = Li, R = But; M = Na−Cs, R = CH2C6H5) afforded the imido-bridged dimers [{U-(TrenTIPS)(μ-N[H]M)}2] [M = L −Cs (2a−e)]. Treatmentof 2c (M = K) with 2 equiv of 15 crown-5 ether (15C5) afforde...

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Bibliographic Details
Main Authors:	King, David M., McMaster, Jonathan, Tuna, Floriana, McInnes, Eric J.L., Lewis, William, Blake, Alexander J., Liddle, Stephen T.
Format:	Article
Published:	American Chemical Society 2014
Online Access:	https://eprints.nottingham.ac.uk/35876/

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