Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings

This study aims to design an optimal polyelectrolyte multilayer film of poly-L-lysine (PLL) and hyaluronic acid(HA) as an anti-inflammatory cytokine release system in order to decrease the implant failure due to any immune reactions. The chemical modification of the HA with aldehyde moieties allows...

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Main Authors: Knopf-Marques, Helena, Singh, Sonali, Htwe, Su Su, Wolfova, Lucie, Buffa, Radovan, Bacharouche, Jalal, Francius, Grégory, Voegel, Jean-Claude, Schaaf, Pierre, Ghaemmaghami, Amir M., Vrana, Nihal E., Lavalle, Philippe
Format: Article
Published: American Chemical Society 2016
Online Access:https://eprints.nottingham.ac.uk/34683/
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author Knopf-Marques, Helena
Singh, Sonali
Htwe, Su Su
Wolfova, Lucie
Buffa, Radovan
Bacharouche, Jalal
Francius, Grégory
Voegel, Jean-Claude
Schaaf, Pierre
Ghaemmaghami, Amir M.
Vrana, Nihal E.
Lavalle, Philippe
author_facet Knopf-Marques, Helena
Singh, Sonali
Htwe, Su Su
Wolfova, Lucie
Buffa, Radovan
Bacharouche, Jalal
Francius, Grégory
Voegel, Jean-Claude
Schaaf, Pierre
Ghaemmaghami, Amir M.
Vrana, Nihal E.
Lavalle, Philippe
author_sort Knopf-Marques, Helena
building Nottingham Research Data Repository
collection Online Access
description This study aims to design an optimal polyelectrolyte multilayer film of poly-L-lysine (PLL) and hyaluronic acid(HA) as an anti-inflammatory cytokine release system in order to decrease the implant failure due to any immune reactions. The chemical modification of the HA with aldehyde moieties allows self-cross-linking of the film and an improvement in the mechanical properties of the film. The cross-linking of the film and the release of immunomodulatory cytokine (IL-4) stimulate the differentiation of primary human monocytes seeded on the films into pro-healing macrophages phenotype. This induces the production of antiinflammatory cytokines (IL1-RA and CCL18) and the decrease of proinflammatory cytokines secreted (IL-12, TNF-α, and IL-1β). Moreover, we demonstrate that cross-linking PLL/HA film using HA-aldehyde is already effective by itself to limit inflammatory processes. Finally, this functionalized self-cross-linked PLL/HA-aldehyde films constitutes an innovative and efficient candidate for immunomodulation of any kind of implants of various architecture and properties.
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institution University of Nottingham Malaysia Campus
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publishDate 2016
publisher American Chemical Society
recordtype eprints
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spelling nottingham-346832020-05-04T17:56:48Z https://eprints.nottingham.ac.uk/34683/ Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings Knopf-Marques, Helena Singh, Sonali Htwe, Su Su Wolfova, Lucie Buffa, Radovan Bacharouche, Jalal Francius, Grégory Voegel, Jean-Claude Schaaf, Pierre Ghaemmaghami, Amir M. Vrana, Nihal E. Lavalle, Philippe This study aims to design an optimal polyelectrolyte multilayer film of poly-L-lysine (PLL) and hyaluronic acid(HA) as an anti-inflammatory cytokine release system in order to decrease the implant failure due to any immune reactions. The chemical modification of the HA with aldehyde moieties allows self-cross-linking of the film and an improvement in the mechanical properties of the film. The cross-linking of the film and the release of immunomodulatory cytokine (IL-4) stimulate the differentiation of primary human monocytes seeded on the films into pro-healing macrophages phenotype. This induces the production of antiinflammatory cytokines (IL1-RA and CCL18) and the decrease of proinflammatory cytokines secreted (IL-12, TNF-α, and IL-1β). Moreover, we demonstrate that cross-linking PLL/HA film using HA-aldehyde is already effective by itself to limit inflammatory processes. Finally, this functionalized self-cross-linked PLL/HA-aldehyde films constitutes an innovative and efficient candidate for immunomodulation of any kind of implants of various architecture and properties. American Chemical Society 2016-06-13 Article PeerReviewed Knopf-Marques, Helena, Singh, Sonali, Htwe, Su Su, Wolfova, Lucie, Buffa, Radovan, Bacharouche, Jalal, Francius, Grégory, Voegel, Jean-Claude, Schaaf, Pierre, Ghaemmaghami, Amir M., Vrana, Nihal E. and Lavalle, Philippe (2016) Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings. Biomacromolecules, 17 (6). pp. 2189-2198. ISSN 1525-7797 http://pubs.acs.org/doi/abs/10.1021/acs.biomac.6b00429 doi:10.1021/acs.biomac.6b00429 doi:10.1021/acs.biomac.6b00429
spellingShingle Knopf-Marques, Helena
Singh, Sonali
Htwe, Su Su
Wolfova, Lucie
Buffa, Radovan
Bacharouche, Jalal
Francius, Grégory
Voegel, Jean-Claude
Schaaf, Pierre
Ghaemmaghami, Amir M.
Vrana, Nihal E.
Lavalle, Philippe
Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
title Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
title_full Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
title_fullStr Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
title_full_unstemmed Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
title_short Immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
title_sort immunomodulation with self-crosslinked polyelectrolyte multilayer-based coatings
url https://eprints.nottingham.ac.uk/34683/
https://eprints.nottingham.ac.uk/34683/
https://eprints.nottingham.ac.uk/34683/