Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties

Porous PEEK structures with approximately 85% open porosity have been made using PEEK-OPTIMA® powder and a particulate leaching technique using porous, near-spherical, sodium chloride beads. A novel manufacturing approach is presented and compared with a traditional dry mixing method. Irrespective o...

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Main Authors: Siddiq, Abdur R., Kennedy, Andrew R.
Format: Article
Published: Elsevier 2015
Online Access:https://eprints.nottingham.ac.uk/34449/
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author Siddiq, Abdur R.
Kennedy, Andrew R.
author_facet Siddiq, Abdur R.
Kennedy, Andrew R.
author_sort Siddiq, Abdur R.
building Nottingham Research Data Repository
collection Online Access
description Porous PEEK structures with approximately 85% open porosity have been made using PEEK-OPTIMA® powder and a particulate leaching technique using porous, near-spherical, sodium chloride beads. A novel manufacturing approach is presented and compared with a traditional dry mixing method. Irrespective of the method used, the use of near-spherical beads with a fairly narrow size range results in uniform pore structures. However the integration, by tapping, of fine PEEK into a pre-existing network salt beads, followed by compaction and “sintering”, produces porous structures with excellent repeatability and homogeneity of density; more uniform pore and strut sizes; an improved and predictable level of connectivity via the formation of “windows” between the cells; faster salt removal rates and lower levels of residual salt. Although tapped samples show a compressive yield stress N1 MPa and stiffness N30 MPa for samples with 84% porosity, the presence of windows in the cell walls means that tapped structures show lower strengths and lower stiffnesses than equivalent structures made by mixing.
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spelling nottingham-344492020-05-04T16:59:36Z https://eprints.nottingham.ac.uk/34449/ Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties Siddiq, Abdur R. Kennedy, Andrew R. Porous PEEK structures with approximately 85% open porosity have been made using PEEK-OPTIMA® powder and a particulate leaching technique using porous, near-spherical, sodium chloride beads. A novel manufacturing approach is presented and compared with a traditional dry mixing method. Irrespective of the method used, the use of near-spherical beads with a fairly narrow size range results in uniform pore structures. However the integration, by tapping, of fine PEEK into a pre-existing network salt beads, followed by compaction and “sintering”, produces porous structures with excellent repeatability and homogeneity of density; more uniform pore and strut sizes; an improved and predictable level of connectivity via the formation of “windows” between the cells; faster salt removal rates and lower levels of residual salt. Although tapped samples show a compressive yield stress N1 MPa and stiffness N30 MPa for samples with 84% porosity, the presence of windows in the cell walls means that tapped structures show lower strengths and lower stiffnesses than equivalent structures made by mixing. Elsevier 2015-02-01 Article PeerReviewed Siddiq, Abdur R. and Kennedy, Andrew R. (2015) Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties. Materials Science and Engineering: C, 47 . pp. 180-188. ISSN 0928-4931 http://www.sciencedirect.com/science/article/pii/S0928493114007450 doi:10.1016/j.msec.2014.11.044 doi:10.1016/j.msec.2014.11.044
spellingShingle Siddiq, Abdur R.
Kennedy, Andrew R.
Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
title Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
title_full Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
title_fullStr Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
title_full_unstemmed Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
title_short Porous poly-ether ether ketone (PEEK) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
title_sort porous poly-ether ether ketone (peek) manufactured by a novel powder route using near-spherical salt bead porogens: characterisation and mechanical properties
url https://eprints.nottingham.ac.uk/34449/
https://eprints.nottingham.ac.uk/34449/
https://eprints.nottingham.ac.uk/34449/