Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles

The study of the paleomagnetic signal recorded by rocks allows scientists to understand Earth’s past magnetic field and the formation of the geodynamo. The magnetic recording fidelity of this signal is dependent on the magnetic domain state it adopts. The most prevalent example found in nature is th...

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Main Authors: Almeida, Trevor P., Muxworthy, Adrian R., Kovacs, Andras, Williams, Wyn, Brown, Paul D., Dunin-Borkowski, Rafal E.
Format: Article
Published: American Association for the Advancement of Science 2016
Subjects:
Online Access:https://eprints.nottingham.ac.uk/34254/
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author Almeida, Trevor P.
Muxworthy, Adrian R.
Kovacs, Andras
Williams, Wyn
Brown, Paul D.
Dunin-Borkowski, Rafal E.
author_facet Almeida, Trevor P.
Muxworthy, Adrian R.
Kovacs, Andras
Williams, Wyn
Brown, Paul D.
Dunin-Borkowski, Rafal E.
author_sort Almeida, Trevor P.
building Nottingham Research Data Repository
collection Online Access
description The study of the paleomagnetic signal recorded by rocks allows scientists to understand Earth’s past magnetic field and the formation of the geodynamo. The magnetic recording fidelity of this signal is dependent on the magnetic domain state it adopts. The most prevalent example found in nature is the pseudo–single-domain (PSD) structure, yet its recording fidelity is poorly understood. Here, the thermoremanent behavior of PSD magnetite (Fe3O4) particles, which dominate the magnetic signatures of many rock lithologies, is investigated using electron holography. This study provides spatially resolved magnetic information from individual Fe3O4 grains as a function of temperature, which has been previously inaccessible. A small exemplar Fe3O4 grain (~150 nm) exhibits dynamic movement of its magnetic vortex structure above 400°C, recovering its original state upon cooling, whereas a larger exemplar Fe3O4 grain (~250 nm) is shown to retain its vortex state on heating to 550°C, close to the Curie temperature of 580°C. Hence, we demonstrate that Fe3O4 grains containing vortex structures are indeed reliable recorders of paleodirectional and paleointensity information, and the presence of PSD magnetic signals does not preclude the successful recovery of paleomagnetic signals.
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spelling nottingham-342542020-05-04T17:46:22Z https://eprints.nottingham.ac.uk/34254/ Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles Almeida, Trevor P. Muxworthy, Adrian R. Kovacs, Andras Williams, Wyn Brown, Paul D. Dunin-Borkowski, Rafal E. The study of the paleomagnetic signal recorded by rocks allows scientists to understand Earth’s past magnetic field and the formation of the geodynamo. The magnetic recording fidelity of this signal is dependent on the magnetic domain state it adopts. The most prevalent example found in nature is the pseudo–single-domain (PSD) structure, yet its recording fidelity is poorly understood. Here, the thermoremanent behavior of PSD magnetite (Fe3O4) particles, which dominate the magnetic signatures of many rock lithologies, is investigated using electron holography. This study provides spatially resolved magnetic information from individual Fe3O4 grains as a function of temperature, which has been previously inaccessible. A small exemplar Fe3O4 grain (~150 nm) exhibits dynamic movement of its magnetic vortex structure above 400°C, recovering its original state upon cooling, whereas a larger exemplar Fe3O4 grain (~250 nm) is shown to retain its vortex state on heating to 550°C, close to the Curie temperature of 580°C. Hence, we demonstrate that Fe3O4 grains containing vortex structures are indeed reliable recorders of paleodirectional and paleointensity information, and the presence of PSD magnetic signals does not preclude the successful recovery of paleomagnetic signals. American Association for the Advancement of Science 2016-04-15 Article PeerReviewed Almeida, Trevor P., Muxworthy, Adrian R., Kovacs, Andras, Williams, Wyn, Brown, Paul D. and Dunin-Borkowski, Rafal E. (2016) Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles. Science Advances, 2 (4). e1501801. ISSN 2375-2548 Palaeomagnetism magnetite nanoparticles in situ transmission electron microscopy off-axis electron holography pseudo–single-domain states thermo-remanent magnetisation thermomagnetic behavior http://advances.sciencemag.org/content/2/4/e1501801 doi:10.1126/sciadv.1501801 doi:10.1126/sciadv.1501801
spellingShingle Palaeomagnetism
magnetite
nanoparticles
in situ transmission electron microscopy
off-axis electron holography
pseudo–single-domain states
thermo-remanent magnetisation
thermomagnetic behavior
Almeida, Trevor P.
Muxworthy, Adrian R.
Kovacs, Andras
Williams, Wyn
Brown, Paul D.
Dunin-Borkowski, Rafal E.
Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
title Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
title_full Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
title_fullStr Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
title_full_unstemmed Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
title_short Direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
title_sort direct visualization of the thermomagnetic behavior of pseudo-single-domain magnetite particles
topic Palaeomagnetism
magnetite
nanoparticles
in situ transmission electron microscopy
off-axis electron holography
pseudo–single-domain states
thermo-remanent magnetisation
thermomagnetic behavior
url https://eprints.nottingham.ac.uk/34254/
https://eprints.nottingham.ac.uk/34254/
https://eprints.nottingham.ac.uk/34254/