Measuring proton shift tensors with ultrafast MAS NMR
A new proton anisotropic-isotropic shift correlation experiment is described which operates with ultrafast MAS, resulting in good resolution of isotropic proton shifts in the detection dimension. The new experiment makes use of a recoupling sequence designed using symmetry principles which reintrodu...
| Main Authors: | , , , |
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| Format: | Article |
| Published: |
Elsevier
2013
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| Online Access: | https://eprints.nottingham.ac.uk/3277/ |
| _version_ | 1848790991707832320 |
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| author | Miah, Habeeba K. Bennett, David A. Iuga, Dinu Titman, Jeremy J. |
| author_facet | Miah, Habeeba K. Bennett, David A. Iuga, Dinu Titman, Jeremy J. |
| author_sort | Miah, Habeeba K. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | A new proton anisotropic-isotropic shift correlation experiment is described which operates with ultrafast MAS, resulting in good resolution of isotropic proton shifts in the detection dimension. The new experiment makes use of a recoupling sequence designed using symmetry principles which reintroduces the proton chemical shift anisotropy in the indirect dimension. The experiment has been used to measure the proton shift tensor parameters for the OH hydrogen-bonded protons in tyrosine.HCl and citric acid at Larmor frequencies of up to 850 MHz. |
| first_indexed | 2025-11-14T18:21:25Z |
| format | Article |
| id | nottingham-3277 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T18:21:25Z |
| publishDate | 2013 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-32772020-05-04T16:37:53Z https://eprints.nottingham.ac.uk/3277/ Measuring proton shift tensors with ultrafast MAS NMR Miah, Habeeba K. Bennett, David A. Iuga, Dinu Titman, Jeremy J. A new proton anisotropic-isotropic shift correlation experiment is described which operates with ultrafast MAS, resulting in good resolution of isotropic proton shifts in the detection dimension. The new experiment makes use of a recoupling sequence designed using symmetry principles which reintroduces the proton chemical shift anisotropy in the indirect dimension. The experiment has been used to measure the proton shift tensor parameters for the OH hydrogen-bonded protons in tyrosine.HCl and citric acid at Larmor frequencies of up to 850 MHz. Elsevier 2013-07-18 Article PeerReviewed Miah, Habeeba K., Bennett, David A., Iuga, Dinu and Titman, Jeremy J. (2013) Measuring proton shift tensors with ultrafast MAS NMR. Journal of Magnetic Resonance, 235 . pp. 1-5. ISSN 1090-7807 http://www.sciencedirect.com/science/article/pii/S1090780713001742 doi:10.1016/j.jmr.2013.07.005 doi:10.1016/j.jmr.2013.07.005 |
| spellingShingle | Miah, Habeeba K. Bennett, David A. Iuga, Dinu Titman, Jeremy J. Measuring proton shift tensors with ultrafast MAS NMR |
| title | Measuring proton shift tensors with ultrafast MAS NMR |
| title_full | Measuring proton shift tensors with ultrafast MAS NMR |
| title_fullStr | Measuring proton shift tensors with ultrafast MAS NMR |
| title_full_unstemmed | Measuring proton shift tensors with ultrafast MAS NMR |
| title_short | Measuring proton shift tensors with ultrafast MAS NMR |
| title_sort | measuring proton shift tensors with ultrafast mas nmr |
| url | https://eprints.nottingham.ac.uk/3277/ https://eprints.nottingham.ac.uk/3277/ https://eprints.nottingham.ac.uk/3277/ |