Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, whi...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2016
|
| Subjects: | |
| Online Access: | https://eprints.nottingham.ac.uk/32411/ |
| _version_ | 1848794401163182080 |
|---|---|
| author | O'Connor, Alice E. Mirzadeh, Nedaossadat Bhargava, Suresh Easun, Timothy L. Schröder, Martin Blake, Alexander J. |
| author_facet | O'Connor, Alice E. Mirzadeh, Nedaossadat Bhargava, Suresh Easun, Timothy L. Schröder, Martin Blake, Alexander J. |
| author_sort | O'Connor, Alice E. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure. |
| first_indexed | 2025-11-14T19:15:36Z |
| format | Article |
| id | nottingham-32411 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T19:15:36Z |
| publishDate | 2016 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-324112017-10-14T07:54:49Z https://eprints.nottingham.ac.uk/32411/ Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study O'Connor, Alice E. Mirzadeh, Nedaossadat Bhargava, Suresh Easun, Timothy L. Schröder, Martin Blake, Alexander J. High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure. Royal Society of Chemistry 2016-03-11 Article PeerReviewed application/pdf en cc_by https://eprints.nottingham.ac.uk/32411/8/c6cc00923a.pdf O'Connor, Alice E., Mirzadeh, Nedaossadat, Bhargava, Suresh, Easun, Timothy L., Schröder, Martin and Blake, Alexander J. (2016) Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications, 52 . pp. 6769-6772. ISSN 1364-548X High Pressure Gold Complexes Structure Determination Spectroscopy Intermolecular Interactions http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00923A#!divAbstract11 doi:10.1039/C6CC00923A doi:10.1039/C6CC00923A |
| spellingShingle | High Pressure Gold Complexes Structure Determination Spectroscopy Intermolecular Interactions O'Connor, Alice E. Mirzadeh, Nedaossadat Bhargava, Suresh Easun, Timothy L. Schröder, Martin Blake, Alexander J. Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| title | Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| title_full | Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| title_fullStr | Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| title_full_unstemmed | Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| title_short | Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| title_sort | aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study |
| topic | High Pressure Gold Complexes Structure Determination Spectroscopy Intermolecular Interactions |
| url | https://eprints.nottingham.ac.uk/32411/ https://eprints.nottingham.ac.uk/32411/ https://eprints.nottingham.ac.uk/32411/ |