Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines

Cu-catalyzed three-component couplings of vinylazaarenes, B2(pin)2, and N-Boc imines are described. Oxidation of the initially formed boronate gives azaarene-containing, Boc-protected amino alcohols with reasonable to good diastereoselectivities.

Bibliographic Details
Main Authors: Smith, Joshua J., Best, Daniel, Lam, Hon Wai
Format: Article
Published: Royal Society of Chemistry 2016
Online Access:https://eprints.nottingham.ac.uk/31806/
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author Smith, Joshua J.
Best, Daniel
Lam, Hon Wai
author_facet Smith, Joshua J.
Best, Daniel
Lam, Hon Wai
author_sort Smith, Joshua J.
building Nottingham Research Data Repository
collection Online Access
description Cu-catalyzed three-component couplings of vinylazaarenes, B2(pin)2, and N-Boc imines are described. Oxidation of the initially formed boronate gives azaarene-containing, Boc-protected amino alcohols with reasonable to good diastereoselectivities.
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spelling nottingham-318062020-05-04T17:36:50Z https://eprints.nottingham.ac.uk/31806/ Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines Smith, Joshua J. Best, Daniel Lam, Hon Wai Cu-catalyzed three-component couplings of vinylazaarenes, B2(pin)2, and N-Boc imines are described. Oxidation of the initially formed boronate gives azaarene-containing, Boc-protected amino alcohols with reasonable to good diastereoselectivities. Royal Society of Chemistry 2016-02-17 Article PeerReviewed Smith, Joshua J., Best, Daniel and Lam, Hon Wai (2016) Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines. Chemical Communications . ISSN 1364-548X http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00603E#!divAbstract doi:10.1039/C6CC00603E doi:10.1039/C6CC00603E
spellingShingle Smith, Joshua J.
Best, Daniel
Lam, Hon Wai
Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
title Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
title_full Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
title_fullStr Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
title_full_unstemmed Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
title_short Copper-catalyzed borylative coupling of vinylazaarenes and N-Boc imines
title_sort copper-catalyzed borylative coupling of vinylazaarenes and n-boc imines
url https://eprints.nottingham.ac.uk/31806/
https://eprints.nottingham.ac.uk/31806/
https://eprints.nottingham.ac.uk/31806/