Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines

The reaction of enamines and bromoquinones in the presence of copper(II) acetate and potassium carbonate results in a regiospecific synthesis of indolequinones. The reaction is broad in scope and scalable and provides a route to the core structure that is present in several biologically interesting...

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Main Authors: Inman, Martyn, Moody, Christopher J.
Format: Article
Published: Wiley-VCH Verlag 2013
Subjects:
Online Access:https://eprints.nottingham.ac.uk/3176/
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author Inman, Martyn
Moody, Christopher J.
author_facet Inman, Martyn
Moody, Christopher J.
author_sort Inman, Martyn
building Nottingham Research Data Repository
collection Online Access
description The reaction of enamines and bromoquinones in the presence of copper(II) acetate and potassium carbonate results in a regiospecific synthesis of indolequinones. The reaction is broad in scope and scalable and provides a route to the core structure that is present in several biologically interesting natural and synthetic compounds.
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spelling nottingham-31762020-05-04T20:19:24Z https://eprints.nottingham.ac.uk/3176/ Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines Inman, Martyn Moody, Christopher J. The reaction of enamines and bromoquinones in the presence of copper(II) acetate and potassium carbonate results in a regiospecific synthesis of indolequinones. The reaction is broad in scope and scalable and provides a route to the core structure that is present in several biologically interesting natural and synthetic compounds. Wiley-VCH Verlag 2013-04 Article PeerReviewed Inman, Martyn and Moody, Christopher J. (2013) Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines. European Journal of Organic Chemistry, 2013 (11). pp. 2179-2187. ISSN 1434-193X Synthetic methods Cyclization Nitrogen heterocycles Quinones Copper http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201201597/full doi:10.1002/ejoc.201201597 doi:10.1002/ejoc.201201597
spellingShingle Synthetic methods
Cyclization
Nitrogen heterocycles
Quinones
Copper
Inman, Martyn
Moody, Christopher J.
Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines
title Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines
title_full Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines
title_fullStr Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines
title_full_unstemmed Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines
title_short Copper(II)-mediated synthesis of indolequinones from bromoquinones and enamines
title_sort copper(ii)-mediated synthesis of indolequinones from bromoquinones and enamines
topic Synthetic methods
Cyclization
Nitrogen heterocycles
Quinones
Copper
url https://eprints.nottingham.ac.uk/3176/
https://eprints.nottingham.ac.uk/3176/
https://eprints.nottingham.ac.uk/3176/