Unique determination of “subatomic” contrast by imaging covalent backbonding

The origin of so-called “subatomic” resolution in dynamic force microscopy has remained controversial since its first observation in 2000. A number of detailed experimental and theoretical studies have identified different possible physicochemical mechanisms potentially giving rise to subatomic cont...

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Main Authors: Sweetman, Adam, Rahe, Philipp, Moriarty, Philip
Format: Article
Published: American Chemical Society 2014
Subjects:
Online Access:https://eprints.nottingham.ac.uk/31701/
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author Sweetman, Adam
Rahe, Philipp
Moriarty, Philip
author_facet Sweetman, Adam
Rahe, Philipp
Moriarty, Philip
author_sort Sweetman, Adam
building Nottingham Research Data Repository
collection Online Access
description The origin of so-called “subatomic” resolution in dynamic force microscopy has remained controversial since its first observation in 2000. A number of detailed experimental and theoretical studies have identified different possible physicochemical mechanisms potentially giving rise to subatomic contrast. In this study, for the first time we are able to assign the origin of a specific instance of subatomic contrast as being due to the back bonding of a surface atom in the tip−sample junction.
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spelling nottingham-317012020-05-04T16:44:49Z https://eprints.nottingham.ac.uk/31701/ Unique determination of “subatomic” contrast by imaging covalent backbonding Sweetman, Adam Rahe, Philipp Moriarty, Philip The origin of so-called “subatomic” resolution in dynamic force microscopy has remained controversial since its first observation in 2000. A number of detailed experimental and theoretical studies have identified different possible physicochemical mechanisms potentially giving rise to subatomic contrast. In this study, for the first time we are able to assign the origin of a specific instance of subatomic contrast as being due to the back bonding of a surface atom in the tip−sample junction. American Chemical Society 2014-03-14 Article PeerReviewed Sweetman, Adam, Rahe, Philipp and Moriarty, Philip (2014) Unique determination of “subatomic” contrast by imaging covalent backbonding. Nano Letters, 14 (5). pp. 2265-2270. ISSN 1530-6984 NC-AFM; DFM; subatomic; Si(111); qPlus; UHV http://pubs.acs.org/doi/abs/10.1021/nl4041803 doi:10.1021/nl4041803 doi:10.1021/nl4041803
spellingShingle NC-AFM; DFM; subatomic; Si(111); qPlus; UHV
Sweetman, Adam
Rahe, Philipp
Moriarty, Philip
Unique determination of “subatomic” contrast by imaging covalent backbonding
title Unique determination of “subatomic” contrast by imaging covalent backbonding
title_full Unique determination of “subatomic” contrast by imaging covalent backbonding
title_fullStr Unique determination of “subatomic” contrast by imaging covalent backbonding
title_full_unstemmed Unique determination of “subatomic” contrast by imaging covalent backbonding
title_short Unique determination of “subatomic” contrast by imaging covalent backbonding
title_sort unique determination of “subatomic” contrast by imaging covalent backbonding
topic NC-AFM; DFM; subatomic; Si(111); qPlus; UHV
url https://eprints.nottingham.ac.uk/31701/
https://eprints.nottingham.ac.uk/31701/
https://eprints.nottingham.ac.uk/31701/