Enantioselective synthesis of allylboronates and allylic alcohols by copper-catalyzed 1,6-boration

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Enantioselective synthesis of allylboronates and allylic alcohols by copper-catalyzed 1,6-boration

Chiral secondary allylboronates are obtained in high enantioselectivities by the copper-catalyzed 1,6-boration of electron-deficient dienes with B2(pin)2. The reactions proceed efficiently using catalyst loadings as low as 0.0049 mol%. The allylboronates may be oxidized to the allylic alcohols, and...

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Bibliographic Details
Main Authors:	Luo, Yunfei, Roy, Iain D., Madec, Amaël G.E., Lam, Hon Wai
Format:	Article
Published:	Wiley-VCH Verlag 2014
Online Access:	https://eprints.nottingham.ac.uk/31656/

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