Understanding anionic Chugaev elimination in pericyclic tetracene formation

QR Code

Understanding anionic Chugaev elimination in pericyclic tetracene formation

The reaction pathway for the formation of tetracenes from the diols 1,2-C6H4(CHOHC≡CAr)2 , LiHDMS, CS2 and MeI has been modelled by computational methods at the CBS-QB3 level of theory. Comparison of PhCHOC(=S)YCCPh (Y = S- or SMe) indicates a slight kinetic advantage for the anionic system towards...

Full description

Bibliographic Details
Main Authors:	Burroughs, Laurence, Ritchie, John, Woodward, Simon
Format:	Article
Published:	Elsevier 2016
Online Access:	https://eprints.nottingham.ac.uk/31578/

Similar Items

Anionic sigmatropic-electrocyclic-Chugaev cascades: accessing 12-aryl-5-(methylthiocarbonylthio)tetracenes and a related anthra[2,3-b]thiophene
by: Burroughs, Laurence, et al.
Published: (2015)

Straightforward synthesis of 2- and 2,8-substituted tetracenes
by: Woodward, Simon, et al.
Published: (2017)

Synthesis of 2-bromo-8-methyltetracene and investigation into C-Br functionalisation in tetracene precursors
by: Shine, Jonathan
Published: (2017)

One-pot Cannizzaro cascade synthesis of ortho-Fused Cycloocta-2,5-dien-1-ones from 2-Bromo(hetero)aryl aldehydes
by: Burroughs, Laurence, et al.
Published: (2015)

Diversification of ortho-fused cycloocta-2,5-dien-1-one cores and 8 to 6-Ring conversion by sigma bond C-C cleavage
by: Eccleshare, Lee, et al.
Published: (2016)

Efficient preparation of TMSCCl2Br and its use in dichlorocyclopropanation of electron deficient alkenes
by: Lee, Darren S., et al.
Published: (2016)

Efficient synthesis of 2,5-dicarbonyl derivatives of 3,4-ethylenedithiothiophene (EDTT) via addition-elimination reaction
by: Al-jumaili, Mustafa A-jabbar, et al.
Published: (2017)

Alliance ethics to gain survival and competitive advantage: Eliminating the old economy, achieving the new!
by: Dickie, Carolyn, et al.
Published: (2010)

Iterated elimination procedures
by: Luo, Xiao, et al.
Published: (2019)

Elimination of burr formation during end milling of Polymethyl Methacrylate (PMMA) through high speed machining
by: Amin, A. K. M. Nurul, et al.
Published: (2011)

Biofilm formation of multidrug-resistant Staphylococcus aureus on stainless steel surfaces and the effect of disinfectants in eliminating biofilm
by: Jamaludin, Nur Syifa'
Published: (2019)

The effect of zinc to aluminium ratio and concentration of the anion on the formation of zinc-aluminium-4-chlorophenoxy acetate nanocomposite
by: Hussein, Mohd Zobir, et al.
Published: (2005)

Low-cost and sustainable organic thermoelectrics based on low-dimensional molecular metals
by: Huewe, Florian, et al.
Published: (2017)

Distribution of completion and elimination of horses participating in different distance of endurance race, and causes of elimination
by: Mohd Noor, Mohd Akmal
Published: (2015)

Eliminating Internet weakness in education
by: Hameed, Shihab A.
Published: (2011)

Paul's understanding of spiritual formation: Christian formation and impartation
by: Chung, Michael
Published: (2009)

Receptors for the extraction of the hexachloroplatinate anion
by: Bell, Katherine Jane
Published: (2008)

Synthesis, structural elucidation and anion binding studies of isophthalamide derivatives as potential receptor for chromate anions
by: Maisara Abdul Kadir,, et al.
Published: (2019)

Understand the effect of the confinedtrifluoromethane sulfonate (OTf−) anions by the adjacent MXene nanosheets on oriented design of Zn ion storage
by: Liu, Xin, et al.
Published: (2024)

Characteristics of drift eliminators of an evaporative condenser
by: Singh, A. K., et al.
Published: (1993)

Effective rabies elimination strategy needed
by: Wong, James
Published: (2023)

Understanding agarwood formation and its challenges
by: Rasool, Saiema, et al.
Published: (2016)

Incorporation of Molybdate Anion into -FeOOH
by: Carroll, Dale, et al.
Published: (2008)

Viscoelastic properties of anionic brominated surfactants
by: Larry Lee,, et al.
Published: (2010)

Stably coating loose and electronegative thin layer on anion exchange membrane for efficient and selective monovalent anion transfer
by: Zhang, H., et al.
Published: (2017)

Redundant Data Elimination in Independent Component Analysis
by: Liu, Xianhua, et al.
Published: (2005)

Re-entrainment in wave-plate mist eliminators
by: B. J., Azzopardi, et al.
Published: (2002)

Rates and causes of elimination in Malaysia endurance horses
by: Mohd Rajdi, Nur Zul Izzati, et al.
Published: (2018)

Targeting energy metabolism to eliminate cancer cells
by: Shahruzaman, Shazwin Hani, et al.
Published: (2018)

Elimination of raindrops effects in infrared sensitive camera
by: Abdullah, Ahmad Sharmi
Published: (2007)

Novel anion-bound borates as lubricant additives
by: Shaw, Katherine
Published: (2016)

Interstellar dehydrogenated PAH anions: vibrational spectra
by: Buragohain, Mridusmita, et al.
Published: (2018)

Calixarene complexes of anion-bridged oligouranyl species
by: DeLaigue, X., et al.
Published: (2004)

Anion-π Interactions of Hexaaryl[3]radialenes
by: Evans, J., et al.
Published: (2012)

Effect of electrolyte on synergism of anionic-surfactant mixture
by: Othman, N., et al.
Published: (2009)

On DABAL-Me₃ promoted formation of amides
by: Dubois, Nathalie, et al.
Published: (2013)

1,4-addition of TMSCCl3to nitroalkenes: efficient reaction conditions and mechanistic understanding
by: Wu, Na, et al.
Published: (2014)

Sulfide elimination by using an aerobic sequencing batch reactor
by: Nissa Dayanah, Mohd Anuar
Published: (2016)

Polymeric Concrete: Complete Elimination of Cement for Sustainable Futures
by: Nuruddin, F, et al.
Published: (2010)

Modelling and control of heterogeneous photocatalytic reactors for VOC elimination
by: Chong, Siew Hui
Published: (2009)