Stereoselective synthesis of tetrahydroindolizines via catalytic formation of pyridinium ylides from diazo compounds

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Stereoselective synthesis of tetrahydroindolizines via catalytic formation of pyridinium ylides from diazo compounds

Commercially available iron (III) and copper (I) complexes catalyze new multicomponent cycloadditions between diazo compounds, pyridines and electrophilic alkenes to give alkaloid-inspired tetrahydroindolizidines in high yields and diastereoselectivities. Hitherto, catalytic formation of versatile p...

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Bibliographic Details
Main Authors:	Day, Jonathan, McKeever-Abbas, Ben, Dowden, James
Format:	Article
Published:	Wiley-VCH Verlag 2016
Subjects:	carbenes; cycloaddition; diazo compounds; homogenous catalysis; pyridinium ylides
Online Access:	https://eprints.nottingham.ac.uk/31460/

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