Strategies for MCR image analysis of large hyperspectral data-sets

Polymer microarrays are a key enabling technology for high throughput materials discovery. In this study, multivariate image analysis, specifically multivariate curve resolution (MCR), is applied to the hyperspectral time of flight secondary ion mass spectroscopy (ToF-SIMS) data from eight individua...

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Main Authors: Scurr, David J., Hook, Andrew L., Burley, Jonathan, Williams, Philip M., Anderson, Daniel G., Langer, Robert, Davies, Martyn C., Alexander, Morgan R.
Format: Article
Published: Wiley 2012
Subjects:
Online Access:https://eprints.nottingham.ac.uk/3134/
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author Scurr, David J.
Hook, Andrew L.
Burley, Jonathan
Williams, Philip M.
Anderson, Daniel G.
Langer, Robert
Davies, Martyn C.
Alexander, Morgan R.
author_facet Scurr, David J.
Hook, Andrew L.
Burley, Jonathan
Williams, Philip M.
Anderson, Daniel G.
Langer, Robert
Davies, Martyn C.
Alexander, Morgan R.
author_sort Scurr, David J.
building Nottingham Research Data Repository
collection Online Access
description Polymer microarrays are a key enabling technology for high throughput materials discovery. In this study, multivariate image analysis, specifically multivariate curve resolution (MCR), is applied to the hyperspectral time of flight secondary ion mass spectroscopy (ToF-SIMS) data from eight individual microarray spots. Rather than analysing the data individually, the data-sets are collated and analysed as a single large data-set. Desktop computing is not a practical method for undertaking MCR analysis of such large data-sets due to the constraints of memory and computational overhead. Here, a distributed memory High-Performance Computing facility (HPC) is used. Similar to what is achieved using MCR analysis of individual samples, the results from this consolidated data-set allow clear identification of the substrate material; furthermore, specific chemistries common to different spots are also identified. The application of the HPC facility to the MCR analysis of ToF-SIMS hyperspectral data-sets demonstrates a potential methodology for the analysis of macro-scale data without compromising spatial resolution (data ‘binning’)
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spelling nottingham-31342020-05-04T16:33:14Z https://eprints.nottingham.ac.uk/3134/ Strategies for MCR image analysis of large hyperspectral data-sets Scurr, David J. Hook, Andrew L. Burley, Jonathan Williams, Philip M. Anderson, Daniel G. Langer, Robert Davies, Martyn C. Alexander, Morgan R. Polymer microarrays are a key enabling technology for high throughput materials discovery. In this study, multivariate image analysis, specifically multivariate curve resolution (MCR), is applied to the hyperspectral time of flight secondary ion mass spectroscopy (ToF-SIMS) data from eight individual microarray spots. Rather than analysing the data individually, the data-sets are collated and analysed as a single large data-set. Desktop computing is not a practical method for undertaking MCR analysis of such large data-sets due to the constraints of memory and computational overhead. Here, a distributed memory High-Performance Computing facility (HPC) is used. Similar to what is achieved using MCR analysis of individual samples, the results from this consolidated data-set allow clear identification of the substrate material; furthermore, specific chemistries common to different spots are also identified. The application of the HPC facility to the MCR analysis of ToF-SIMS hyperspectral data-sets demonstrates a potential methodology for the analysis of macro-scale data without compromising spatial resolution (data ‘binning’) Wiley 2012-05-22 Article PeerReviewed Scurr, David J., Hook, Andrew L., Burley, Jonathan, Williams, Philip M., Anderson, Daniel G., Langer, Robert, Davies, Martyn C. and Alexander, Morgan R. (2012) Strategies for MCR image analysis of large hyperspectral data-sets. Surface and Interface Analysis, 45 (1). pp. 466-470. ISSN 0142-2421 Time-of-flight secondary ion mass spectrometry Multivariate curve resolution Microarray High-performance computing http://onlinelibrary.wiley.com/doi/10.1002/sia.5040/full doi:10.1002/sia.5040 doi:10.1002/sia.5040
spellingShingle Time-of-flight secondary ion mass spectrometry
Multivariate curve resolution
Microarray
High-performance computing
Scurr, David J.
Hook, Andrew L.
Burley, Jonathan
Williams, Philip M.
Anderson, Daniel G.
Langer, Robert
Davies, Martyn C.
Alexander, Morgan R.
Strategies for MCR image analysis of large hyperspectral data-sets
title Strategies for MCR image analysis of large hyperspectral data-sets
title_full Strategies for MCR image analysis of large hyperspectral data-sets
title_fullStr Strategies for MCR image analysis of large hyperspectral data-sets
title_full_unstemmed Strategies for MCR image analysis of large hyperspectral data-sets
title_short Strategies for MCR image analysis of large hyperspectral data-sets
title_sort strategies for mcr image analysis of large hyperspectral data-sets
topic Time-of-flight secondary ion mass spectrometry
Multivariate curve resolution
Microarray
High-performance computing
url https://eprints.nottingham.ac.uk/3134/
https://eprints.nottingham.ac.uk/3134/
https://eprints.nottingham.ac.uk/3134/