Alkaline earth complexes of a sterically demanding guanidinate ligand

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Alkaline earth complexes of a sterically demanding guanidinate ligand

The synthesis of the guanidine MesN{C(NCy2)}N(H)Mes (LH; Mes = 2,4,6-Me3C6H2, Cy = cyclohexyl), and its use as a proligand for the synthesis of alkaline earth metal complexes are reported. Described herein are (i) an unusual Hauser base cubane, (ii) a homoleptic and a base-stabilized magnesium compl...

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Bibliographic Details
Main Authors:	Moxey, Graeme J., Blake, Alexander J., Lewis, William, Kays, Deborah L.
Format:	Article
Published:	Wiley 2015
Subjects:	alkaline earth metals N ligands bidentate ligands ligand effects coordiination modes
Online Access:	https://eprints.nottingham.ac.uk/31238/

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