A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

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A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

Bibliographic Details
Main Authors:	Perotto, Carlo U., Marshall, George, Jones, Graham J., Lewis, William, McMaster, Jonathan, Schröder, Martin
Format:	Article
Published:	Royal Society of Chemistry 2015
Online Access:	https://eprints.nottingham.ac.uk/30939/

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