A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases
Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.
| Main Authors: | , , , , , |
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| Format: | Article |
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Royal Society of Chemistry
2015
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| Online Access: | https://eprints.nottingham.ac.uk/30939/ |
| _version_ | 1848794095051341824 |
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| author | Perotto, Carlo U. Marshall, George Jones, Graham J. Lewis, William McMaster, Jonathan Schröder, Martin |
| author_facet | Perotto, Carlo U. Marshall, George Jones, Graham J. Lewis, William McMaster, Jonathan Schröder, Martin |
| author_sort | Perotto, Carlo U. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases. |
| first_indexed | 2025-11-14T19:10:44Z |
| format | Article |
| id | nottingham-30939 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:10:44Z |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-309392020-05-04T17:16:07Z https://eprints.nottingham.ac.uk/30939/ A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases Perotto, Carlo U. Marshall, George Jones, Graham J. Lewis, William McMaster, Jonathan Schröder, Martin Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases. Royal Society of Chemistry 2015-09-30 Article PeerReviewed Perotto, Carlo U., Marshall, George, Jones, Graham J., Lewis, William, McMaster, Jonathan and Schröder, Martin (2015) A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51 . pp. 16988-16991. ISSN 1364-548X http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC05881C#!divAbstract doi:10.1039/c5cc05881c doi:10.1039/c5cc05881c |
| spellingShingle | Perotto, Carlo U. Marshall, George Jones, Graham J. Lewis, William McMaster, Jonathan Schröder, Martin A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases |
| title | A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases |
| title_full | A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases |
| title_fullStr | A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases |
| title_full_unstemmed | A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases |
| title_short | A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases |
| title_sort | ni(i)fe(ii) analogue of the ni-l state of the active site of the [nife] hydrogenases |
| url | https://eprints.nottingham.ac.uk/30939/ https://eprints.nottingham.ac.uk/30939/ https://eprints.nottingham.ac.uk/30939/ |