Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines

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Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines

Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety.The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained wit...

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Bibliographic Details
Main Authors:	Martínez, Jose I., Smith, Joshua S., Hepburn, Hamish B., Lam, Hon Wai
Format:	Article
Published:	Wiley-VCH Verlag 2015
Online Access:	https://eprints.nottingham.ac.uk/30669/

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