Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines
Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety.The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained wit...
| Main Authors: | , , , |
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| Format: | Article |
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Wiley-VCH Verlag
2015
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| Online Access: | https://eprints.nottingham.ac.uk/30669/ |
| _version_ | 1848794033962352640 |
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| author | Martínez, Jose I. Smith, Joshua S. Hepburn, Hamish B. Lam, Hon Wai |
| author_facet | Martínez, Jose I. Smith, Joshua S. Hepburn, Hamish B. Lam, Hon Wai |
| author_sort | Martínez, Jose I. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety.The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained with high enantioselectivities, where a pronounced matched/mismatched effect with the chirality of the allyltrifluoroborate is evident. |
| first_indexed | 2025-11-14T19:09:46Z |
| format | Article |
| id | nottingham-30669 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:09:46Z |
| publishDate | 2015 |
| publisher | Wiley-VCH Verlag |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-306692020-05-04T17:28:12Z https://eprints.nottingham.ac.uk/30669/ Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines Martínez, Jose I. Smith, Joshua S. Hepburn, Hamish B. Lam, Hon Wai Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety.The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained with high enantioselectivities, where a pronounced matched/mismatched effect with the chirality of the allyltrifluoroborate is evident. Wiley-VCH Verlag 2015-12-03 Article PeerReviewed Martínez, Jose I., Smith, Joshua S., Hepburn, Hamish B. and Lam, Hon Wai (2015) Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines. Angewandte Chemie International Edition . ISSN 1433-7851 http://onlinelibrary.wiley.com/doi/10.1002/anie.201508964/full doi:10.1002/anie.201508964 doi:10.1002/anie.201508964 |
| spellingShingle | Martínez, Jose I. Smith, Joshua S. Hepburn, Hamish B. Lam, Hon Wai Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines |
| title | Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines |
| title_full | Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines |
| title_fullStr | Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines |
| title_full_unstemmed | Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines |
| title_short | Chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines |
| title_sort | chain walking of allylrhodium species towards esters during
rhodium-catalyzed nucleophilic allylations of imines |
| url | https://eprints.nottingham.ac.uk/30669/ https://eprints.nottingham.ac.uk/30669/ https://eprints.nottingham.ac.uk/30669/ |