Ligand influences on homoleptic Group 12 m-terphenyl complexes
Three m-terphenyl ligands 2,6-Ar2C6H3 – [Ar = 2,6-Me2C6H3 (2,6-Xyl); 3,5-Me2C6H3 (3,5-Xyl); 2,3,4,5,6-Me5C6 (Pmp)] have been used to stabilise three series of two-coordinate Group 12 diaryl complexes; (2,6-Ar2C6H3)2M [M = Zn, Cd, Hg; Ar = 2,6-Xyl 1-3; 3,5-Xyl 4-6; Pmp 7-9], where differing steric de...
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| Format: | Article |
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Royal Society of Chemistry
2014
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| Online Access: | https://eprints.nottingham.ac.uk/30554/ |
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| author | Blundell, Toby J. Hastings, Fiona R. Gridley, Benjamin M. Moxey, Graeme J. Blake, Alexander J. Lewis, William Kays, Deborah L. |
| author_facet | Blundell, Toby J. Hastings, Fiona R. Gridley, Benjamin M. Moxey, Graeme J. Blake, Alexander J. Lewis, William Kays, Deborah L. |
| author_sort | Blundell, Toby J. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Three m-terphenyl ligands 2,6-Ar2C6H3 – [Ar = 2,6-Me2C6H3 (2,6-Xyl); 3,5-Me2C6H3 (3,5-Xyl); 2,3,4,5,6-Me5C6 (Pmp)] have been used to stabilise three series of two-coordinate Group 12 diaryl complexes; (2,6-Ar2C6H3)2M [M = Zn, Cd, Hg; Ar = 2,6-Xyl 1-3; 3,5-Xyl 4-6; Pmp 7-9], where differing steric demands on the metal centres are imparted. These are the first homoleptic d-block complexes featuring any of these ligands. Complexes 1-9 have been characterised in solution and the solid state; the analysis of structural changes produced by differences in ligand properties is reported. In particular, complexes 4-6 show smaller C–M–C bond angles and contain secondary ligand interactions that are not seen in the analogous complexes 1-3 and 7-9. |
| first_indexed | 2025-11-14T19:09:23Z |
| format | Article |
| id | nottingham-30554 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:09:23Z |
| publishDate | 2014 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-305542020-05-04T16:46:56Z https://eprints.nottingham.ac.uk/30554/ Ligand influences on homoleptic Group 12 m-terphenyl complexes Blundell, Toby J. Hastings, Fiona R. Gridley, Benjamin M. Moxey, Graeme J. Blake, Alexander J. Lewis, William Kays, Deborah L. Three m-terphenyl ligands 2,6-Ar2C6H3 – [Ar = 2,6-Me2C6H3 (2,6-Xyl); 3,5-Me2C6H3 (3,5-Xyl); 2,3,4,5,6-Me5C6 (Pmp)] have been used to stabilise three series of two-coordinate Group 12 diaryl complexes; (2,6-Ar2C6H3)2M [M = Zn, Cd, Hg; Ar = 2,6-Xyl 1-3; 3,5-Xyl 4-6; Pmp 7-9], where differing steric demands on the metal centres are imparted. These are the first homoleptic d-block complexes featuring any of these ligands. Complexes 1-9 have been characterised in solution and the solid state; the analysis of structural changes produced by differences in ligand properties is reported. In particular, complexes 4-6 show smaller C–M–C bond angles and contain secondary ligand interactions that are not seen in the analogous complexes 1-3 and 7-9. Royal Society of Chemistry 2014-04-08 Article PeerReviewed Blundell, Toby J., Hastings, Fiona R., Gridley, Benjamin M., Moxey, Graeme J., Blake, Alexander J., Lewis, William and Kays, Deborah L. (2014) Ligand influences on homoleptic Group 12 m-terphenyl complexes. Dalton Transactions, 43 . pp. 14257-14264. ISSN 1477-9226 http://pubs.rsc.org/en/content/articlelanding/2014/dt/c4dt00647j#!divAbstract doi:10.1039/C4DT00647J doi:10.1039/C4DT00647J |
| spellingShingle | Blundell, Toby J. Hastings, Fiona R. Gridley, Benjamin M. Moxey, Graeme J. Blake, Alexander J. Lewis, William Kays, Deborah L. Ligand influences on homoleptic Group 12 m-terphenyl complexes |
| title | Ligand influences on homoleptic Group 12
m-terphenyl complexes |
| title_full | Ligand influences on homoleptic Group 12
m-terphenyl complexes |
| title_fullStr | Ligand influences on homoleptic Group 12
m-terphenyl complexes |
| title_full_unstemmed | Ligand influences on homoleptic Group 12
m-terphenyl complexes |
| title_short | Ligand influences on homoleptic Group 12
m-terphenyl complexes |
| title_sort | ligand influences on homoleptic group 12
m-terphenyl complexes |
| url | https://eprints.nottingham.ac.uk/30554/ https://eprints.nottingham.ac.uk/30554/ https://eprints.nottingham.ac.uk/30554/ |