Structural chemistry of metal coordination complexes at high pressure
The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids. This review highlights and describes recent advances in high pressure studies of coordination complexes, many of which have been conducted at...
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| Format: | Article |
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Elsevier
2014
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| Online Access: | https://eprints.nottingham.ac.uk/29690/ |
| _version_ | 1848793832643100672 |
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| author | Schröder, Martin |
| author_facet | Schröder, Martin |
| author_sort | Schröder, Martin |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids. This review highlights and describes recent advances in high pressure studies of coordination complexes, many of which have been conducted at synchrotrons or other central facilities. The main focus is on the wide range of geometric changes which occur with pressure. In some cases these changes have associated physical effects, and the review describes materials exhibiting negative linear compressibility, spin cross-over phenomena, magnetism and molecular conduction, as well as detailing the exciting possibilities for future developments in this area of research. |
| first_indexed | 2025-11-14T19:06:34Z |
| format | Article |
| id | nottingham-29690 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:06:34Z |
| publishDate | 2014 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-296902020-05-04T16:53:04Z https://eprints.nottingham.ac.uk/29690/ Structural chemistry of metal coordination complexes at high pressure Schröder, Martin The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids. This review highlights and describes recent advances in high pressure studies of coordination complexes, many of which have been conducted at synchrotrons or other central facilities. The main focus is on the wide range of geometric changes which occur with pressure. In some cases these changes have associated physical effects, and the review describes materials exhibiting negative linear compressibility, spin cross-over phenomena, magnetism and molecular conduction, as well as detailing the exciting possibilities for future developments in this area of research. Elsevier 2014-10-01 Article PeerReviewed Schröder, Martin (2014) Structural chemistry of metal coordination complexes at high pressure. Coordination Chemistry Reviews, 277 . pp. 187-207. ISSN 0010-8545 Synchrotron science; High pressure crystallography; Phase changes; Metal-organic complexes; Organometallic compounds; Supramolecular chemistry http://www.sciencedirect.com/science/article/pii/S0010854514001167 doi:10.1016/j.ccr.2014.04.004 doi:10.1016/j.ccr.2014.04.004 |
| spellingShingle | Synchrotron science; High pressure crystallography; Phase changes; Metal-organic complexes; Organometallic compounds; Supramolecular chemistry Schröder, Martin Structural chemistry of metal coordination complexes at high pressure |
| title | Structural chemistry of metal coordination complexes at high pressure |
| title_full | Structural chemistry of metal coordination complexes at high pressure |
| title_fullStr | Structural chemistry of metal coordination complexes at high pressure |
| title_full_unstemmed | Structural chemistry of metal coordination complexes at high pressure |
| title_short | Structural chemistry of metal coordination complexes at high pressure |
| title_sort | structural chemistry of metal coordination complexes at high pressure |
| topic | Synchrotron science; High pressure crystallography; Phase changes; Metal-organic complexes; Organometallic compounds; Supramolecular chemistry |
| url | https://eprints.nottingham.ac.uk/29690/ https://eprints.nottingham.ac.uk/29690/ https://eprints.nottingham.ac.uk/29690/ |