Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy
We present new potential energy surfaces for the interaction of NO(C 2Π) with each of Ne, Kr, and Xe. The potential energy surfaces have been calculated using second order Møller-Plesset perturbation theory, exploiting a procedure to converge the reference Hartree-Fock wavefunction for the excited s...
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| Format: | Article |
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American Institute of Physics
2015
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| Online Access: | https://eprints.nottingham.ac.uk/28800/ |
| _version_ | 1848793645189169152 |
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| author | Ershova, Olga V. Klos, Jacek Besley, Nicholas A. Wright, Timothy G. |
| author_facet | Ershova, Olga V. Klos, Jacek Besley, Nicholas A. Wright, Timothy G. |
| author_sort | Ershova, Olga V. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | We present new potential energy surfaces for the interaction of NO(C 2Π) with each of Ne, Kr, and Xe. The potential energy surfaces have been calculated using second order Møller-Plesset perturbation theory, exploiting a procedure to converge the reference Hartree-Fock wavefunction for the excited states: the maximum overlap method. The bound rovibrational states obtained from the surfaces are used to simulate the electronic spectra and their appearance is in good agreement with available (2+1) REMPI spectra. We discuss the assignment and appearance of these spectra, comparing to that of NO-Ar. |
| first_indexed | 2025-11-14T19:03:35Z |
| format | Article |
| id | nottingham-28800 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:03:35Z |
| publishDate | 2015 |
| publisher | American Institute of Physics |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-288002020-05-04T17:00:32Z https://eprints.nottingham.ac.uk/28800/ Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy Ershova, Olga V. Klos, Jacek Besley, Nicholas A. Wright, Timothy G. We present new potential energy surfaces for the interaction of NO(C 2Π) with each of Ne, Kr, and Xe. The potential energy surfaces have been calculated using second order Møller-Plesset perturbation theory, exploiting a procedure to converge the reference Hartree-Fock wavefunction for the excited states: the maximum overlap method. The bound rovibrational states obtained from the surfaces are used to simulate the electronic spectra and their appearance is in good agreement with available (2+1) REMPI spectra. We discuss the assignment and appearance of these spectra, comparing to that of NO-Ar. American Institute of Physics 2015-01-21 Article PeerReviewed Ershova, Olga V., Klos, Jacek, Besley, Nicholas A. and Wright, Timothy G. (2015) Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy. Journal of Chemical Physics, 142 (3). 034311/1-034311/15. ISSN 0021-9606 http://scitation.aip.org/content/aip/journal/jcp/142/3/10.1063/1.4905563 doi:10.1063/1.4905563 doi:10.1063/1.4905563 |
| spellingShingle | Ershova, Olga V. Klos, Jacek Besley, Nicholas A. Wright, Timothy G. Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy |
| title | Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy |
| title_full | Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy |
| title_fullStr | Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy |
| title_full_unstemmed | Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy |
| title_short | Interaction of the NO 3pπ (C 2Π) Rydberg state with RG (RG = Ne, Kr, and Xe): potential energy surfaces and spectroscopy |
| title_sort | interaction of the no 3pπ (c 2π) rydberg state with rg (rg = ne, kr, and xe): potential energy surfaces and spectroscopy |
| url | https://eprints.nottingham.ac.uk/28800/ https://eprints.nottingham.ac.uk/28800/ https://eprints.nottingham.ac.uk/28800/ |