The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy
We report (nanosecond) resonance-enhanced multiphoton ionization (REMPI), (nanosecond) zero-kinetic-energy (ZEKE) and (picosecond) time-resolved slow-electron velocity map imaging (tr-SEVI) spectra of fully hydrogenated toluene (Tol-h8) and the deuterated-methyl group isotopologue (α3-Tol-d3). Vibra...
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| Format: | Article |
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American Institute of Physics
2014
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| Online Access: | https://eprints.nottingham.ac.uk/28796/ |
| _version_ | 1848793644083970048 |
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| author | Gardner, Adrian M. Green, Alistair M. Tamé-Reyes, Victor M. Reid, Katharine L. Davies, Julia A. Parkes, Victoria H.K. Wright, Timothy G. |
| author_facet | Gardner, Adrian M. Green, Alistair M. Tamé-Reyes, Victor M. Reid, Katharine L. Davies, Julia A. Parkes, Victoria H.K. Wright, Timothy G. |
| author_sort | Gardner, Adrian M. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | We report (nanosecond) resonance-enhanced multiphoton ionization (REMPI), (nanosecond) zero-kinetic-energy (ZEKE) and (picosecond) time-resolved slow-electron velocity map imaging (tr-SEVI) spectra of fully hydrogenated toluene (Tol-h8) and the deuterated-methyl group isotopologue (α3-Tol-d3). Vibrational assignments are made making use of the activity observed in the ZEKE and tr-SEVI spectra, together with the results from quantum chemical andprevious experimental results.Here, we examine the 700–1500 cm−1 region of the REMPI spectrum, extending our previous work on the region ≤700 cm−1. We provide assignments for the majority of the S1 and cation bands observed, and in particular we gain insight regarding a number of regions where vibrations are coupled via Fermi resonance. We also gain insight into intramolecular vibrational redistribution in this molecule. |
| first_indexed | 2025-11-14T19:03:34Z |
| format | Article |
| id | nottingham-28796 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:03:34Z |
| publishDate | 2014 |
| publisher | American Institute of Physics |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-287962020-05-04T16:44:32Z https://eprints.nottingham.ac.uk/28796/ The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy Gardner, Adrian M. Green, Alistair M. Tamé-Reyes, Victor M. Reid, Katharine L. Davies, Julia A. Parkes, Victoria H.K. Wright, Timothy G. We report (nanosecond) resonance-enhanced multiphoton ionization (REMPI), (nanosecond) zero-kinetic-energy (ZEKE) and (picosecond) time-resolved slow-electron velocity map imaging (tr-SEVI) spectra of fully hydrogenated toluene (Tol-h8) and the deuterated-methyl group isotopologue (α3-Tol-d3). Vibrational assignments are made making use of the activity observed in the ZEKE and tr-SEVI spectra, together with the results from quantum chemical andprevious experimental results.Here, we examine the 700–1500 cm−1 region of the REMPI spectrum, extending our previous work on the region ≤700 cm−1. We provide assignments for the majority of the S1 and cation bands observed, and in particular we gain insight regarding a number of regions where vibrations are coupled via Fermi resonance. We also gain insight into intramolecular vibrational redistribution in this molecule. American Institute of Physics 2014-03-19 Article PeerReviewed Gardner, Adrian M., Green, Alistair M., Tamé-Reyes, Victor M., Reid, Katharine L., Davies, Julia A., Parkes, Victoria H.K. and Wright, Timothy G. (2014) The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy. Journal of Chemical Physics, 140 (11). 114308/1-114308/22. ISSN 0021-9606 http://scitation.aip.org/content/aip/journal/jcp/140/11/10.1063/1.4867970 doi:10.1063/1.4867970 doi:10.1063/1.4867970 |
| spellingShingle | Gardner, Adrian M. Green, Alistair M. Tamé-Reyes, Victor M. Reid, Katharine L. Davies, Julia A. Parkes, Victoria H.K. Wright, Timothy G. The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy |
| title | The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced
multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy |
| title_full | The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced
multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy |
| title_fullStr | The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced
multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy |
| title_full_unstemmed | The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced
multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy |
| title_short | The 700-1500 cm-1 region of the S1 (A1-B-2) state of toluene studied with resonance-enhanced
multiphoton ionization (REMPI), zero-kinetic-energy (ZEKE) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-SEVI) spectroscopy |
| title_sort | 700-1500 cm-1 region of the s1 (a1-b-2) state of toluene studied with resonance-enhanced
multiphoton ionization (rempi), zero-kinetic-energy (zeke) spectroscopy,and time-resolved slow-electron velocity-map imaging (tr-sevi) spectroscopy |
| url | https://eprints.nottingham.ac.uk/28796/ https://eprints.nottingham.ac.uk/28796/ https://eprints.nottingham.ac.uk/28796/ |