Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer
The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products. The process involves a thiazolium salt derived species which is proposed as a radical an...
| Main Authors: | , , |
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| Format: | Article |
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Thieme Chemistry
2013
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| Online Access: | https://eprints.nottingham.ac.uk/2051/ |
| _version_ | 1848790711993892864 |
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| author | Carbone, Giorgio Burnley, James Moses, John E. |
| author_facet | Carbone, Giorgio Burnley, James Moses, John E. |
| author_sort | Carbone, Giorgio |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products. The process involves a thiazolium salt derived species which is proposed as a radical anion relay, with tert-butoxide as the stoichiometric reductant. |
| first_indexed | 2025-11-14T18:16:58Z |
| format | Article |
| id | nottingham-2051 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T18:16:58Z |
| publishDate | 2013 |
| publisher | Thieme Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-20512020-05-04T20:19:52Z https://eprints.nottingham.ac.uk/2051/ Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer Carbone, Giorgio Burnley, James Moses, John E. The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products. The process involves a thiazolium salt derived species which is proposed as a radical anion relay, with tert-butoxide as the stoichiometric reductant. Thieme Chemistry 2013 Article PeerReviewed Carbone, Giorgio, Burnley, James and Moses, John E. (2013) Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer. SYNLETT, 24 (5). pp. 652-656. ISSN 0936-5214 https://www.thieme-connect.de/DOI/DOI?10.1055/s-0032-1318216 doi:10.1055/s-0032-1318216 doi:10.1055/s-0032-1318216 |
| spellingShingle | Carbone, Giorgio Burnley, James Moses, John E. Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| title | Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| title_full | Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| title_fullStr | Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| title_full_unstemmed | Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| title_short | Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| title_sort | catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer |
| url | https://eprints.nottingham.ac.uk/2051/ https://eprints.nottingham.ac.uk/2051/ https://eprints.nottingham.ac.uk/2051/ |