A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides
We report here a new catalytic reaction in which, p-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt deriv...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
Royal Society of Chemistry
2013
|
| Online Access: | https://eprints.nottingham.ac.uk/2050/ |
| _version_ | 1848790711724408832 |
|---|---|
| author | Carbone, Giorgio Burnley, James Moses, John E. |
| author_facet | Carbone, Giorgio Burnley, James Moses, John E. |
| author_sort | Carbone, Giorgio |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | We report here a new catalytic reaction in which, p-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species. |
| first_indexed | 2025-11-14T18:16:58Z |
| format | Article |
| id | nottingham-2050 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T18:16:58Z |
| publishDate | 2013 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-20502020-05-04T16:35:48Z https://eprints.nottingham.ac.uk/2050/ A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides Carbone, Giorgio Burnley, James Moses, John E. We report here a new catalytic reaction in which, p-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species. Royal Society of Chemistry 2013-02-12 Article PeerReviewed Carbone, Giorgio, Burnley, James and Moses, John E. (2013) A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides. Chemical Communications, 49 (27). pp. 2759-2761. ISSN 1364-548X http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc40452h doi:10.1039/c3cc40452h doi:10.1039/c3cc40452h |
| spellingShingle | Carbone, Giorgio Burnley, James Moses, John E. A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| title | A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| title_full | A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| title_fullStr | A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| title_full_unstemmed | A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| title_short | A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| title_sort | catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides |
| url | https://eprints.nottingham.ac.uk/2050/ https://eprints.nottingham.ac.uk/2050/ https://eprints.nottingham.ac.uk/2050/ |