Quantum rotor tunnelling in methyl ethyl ketone and acetophenone studied using field-cycling NMR techniques

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Quantum rotor tunnelling in methyl ethyl ketone and acetophenone studied using field-cycling NMR techniques

In the solid state the rotation of a methyl group is hindered by a potential barrier and at low temperature the rotational motion is characterised by quantum tunnelling. The Pauli Exclusion Principle imposes constraints on the allowable eigenstates of the methyl rotor and leads to a combination of s...

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Bibliographic Details
Main Author:	Abu-Khumra, Sabah
Format:	Thesis (University of Nottingham only)
Language:	English
Published:	2013
Subjects:	Rotational motion Methyl ethyl ketone Quantum tunnelling Tunnelling polarization Dynamic tunnelling polarization
Online Access:	https://eprints.nottingham.ac.uk/14032/

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