New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries

We report on the first synthesis of a new NASICON framework Li(2)Ni(2)(MoO(4))(3) and on the investigation of its electrochemical behavior upon Li extraction coupled with structural analysis. Li(2)Ni(2)( MoO(4))(3) was synthesized by a novel soft-combustion approach involving glycine as a combustion...

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Main Authors:	Begam, K. M., Michael, M. S., Taufiq-Yap, Y. H., Prabaharan, S. R. S.
Format:	Article
Published:	2004
Subjects:	Q Science (General)
Online Access:	http://shdl.mmu.edu.my/2491/

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author	Begam, K. M. Michael, M. S. Taufiq-Yap, Y. H. Prabaharan, S. R. S.
author_facet	Begam, K. M. Michael, M. S. Taufiq-Yap, Y. H. Prabaharan, S. R. S.
author_sort	Begam, K. M.
building	MMU Institutional Repository
collection	Online Access
description	We report on the first synthesis of a new NASICON framework Li(2)Ni(2)(MoO(4))(3) and on the investigation of its electrochemical behavior upon Li extraction coupled with structural analysis. Li(2)Ni(2)( MoO(4))(3) was synthesized by a novel soft-combustion approach involving glycine as a combustion agent and the product was found to crystallize in an orthorhombic structure (space group Pmcn) with lattice parameters alpha = 10.424(4) Angstrom, b = 17.525(1) Angstrom, and c = 5.074(3) Angstrom. Reversible extraction and insertion of lithium from and into the framework structure delivered a reversible capacity of similar to115 mAh/g (4.9-1.5 V window) after the first charge/discharge cycle. (C) 2004 The Electrochemical Society.
first_indexed	2025-11-14T18:06:45Z
format	Article
id	mmu-2491
institution	Multimedia University
institution_category	Local University
last_indexed	2025-11-14T18:06:45Z
publishDate	2004
recordtype	eprints
repository_type	Digital Repository
spelling	mmu-24912011-08-22T02:26:04Z http://shdl.mmu.edu.my/2491/ New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries Begam, K. M. Michael, M. S. Taufiq-Yap, Y. H. Prabaharan, S. R. S. Q Science (General) We report on the first synthesis of a new NASICON framework Li(2)Ni(2)(MoO(4))(3) and on the investigation of its electrochemical behavior upon Li extraction coupled with structural analysis. Li(2)Ni(2)( MoO(4))(3) was synthesized by a novel soft-combustion approach involving glycine as a combustion agent and the product was found to crystallize in an orthorhombic structure (space group Pmcn) with lattice parameters alpha = 10.424(4) Angstrom, b = 17.525(1) Angstrom, and c = 5.074(3) Angstrom. Reversible extraction and insertion of lithium from and into the framework structure delivered a reversible capacity of similar to115 mAh/g (4.9-1.5 V window) after the first charge/discharge cycle. (C) 2004 The Electrochemical Society. 2004 Article NonPeerReviewed Begam, K. M. and Michael, M. S. and Taufiq-Yap, Y. H. and Prabaharan, S. R. S. (2004) New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries. Electrochemical and Solid-State Letters, 7 (8). A242-A246 . ISSN 10990062 http://dx.doi.org/10.1149/1.1760711 doi:10.1149/1.1760711 doi:10.1149/1.1760711
spellingShingle	Q Science (General) Begam, K. M. Michael, M. S. Taufiq-Yap, Y. H. Prabaharan, S. R. S. New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries
title	New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries
title_full	New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries
title_fullStr	New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries
title_full_unstemmed	New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries
title_short	New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries
title_sort	new lithiated nasicon-type li[sub 2]ni[sub 2](moo[sub 4])[sub 3] for rechargeable lithium batteries
topic	Q Science (General)
url	http://shdl.mmu.edu.my/2491/ http://shdl.mmu.edu.my/2491/ http://shdl.mmu.edu.my/2491/

New Lithiated NASICON-Type Li[sub 2]Ni[sub 2](MoO[sub 4])[sub 3] for Rechargeable Lithium Batteries

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