Novel approach to control CdS morphology by simple microwave-solvothermal method
Nanosize CdS powders with different microstructures are prepared in different solvents by using rapid microwave irradiation. Effect of solvents and Cd2+ precursors are to be able to control the particle size, and microstructures of CdS have been investigated by X-ray diffraction and TEM. The differe...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2005
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| Subjects: | |
| Online Access: | http://shdl.mmu.edu.my/2234/ http://shdl.mmu.edu.my/2234/1/1542.pdf |
| Summary: | Nanosize CdS powders with different microstructures are prepared in different solvents by using rapid microwave irradiation. Effect of solvents and Cd2+ precursors are to be able to control the particle size, and microstructures of CdS have been investigated by X-ray diffraction and TEM. The different particle size and morphologies are observed using different Cd2+ precursors in different solvents. TEM micrographs clearly show multiarmed nanorods and spherical shape morphologies of CdS powders are obtained in polar solvent like water (H2O), whereas non-polar polyol solvent like ethylene glycol (EG), prickle and cluster like morphologies of CdS are achieved with different Cd2+ precursors such as CdSO4 and Cd (CH3COO)(2). The spectroscopy studies of nanosize CdS are examined by photo-luminescence spectra. Band gap and the absorption co-efficient for nano CdS is also evaluated from optical absorption studies. (C) 2005 Springer Science + Business Media, Inc. |
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