Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors

Biodegradable solid polymer electrolyte (SPE) systems composed of hydroxylethyl cellulose blended with copper(II) oxide (CuO) and yttrium(III) oxide (Y2O3) nanoparticles as fillers, magnesium trifluoromethane sulfonate salt, and 1-ethyl-3-methylimidazolium trifluoromethane sulfonate ionic liquid wer...

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Main Authors: Chong, Mee Yoke, Arshid, Numan, Chiam, Wen Liew, Ramesh, K., Ramesh, S.
Format: Article
Published: John Wiley & Sons, Inc. 2017
Subjects:
Online Access:http://eprints.intimal.edu.my/681/
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author Chong, Mee Yoke
Arshid, Numan
Chiam, Wen Liew
Ramesh, K.
Ramesh, S.
author_facet Chong, Mee Yoke
Arshid, Numan
Chiam, Wen Liew
Ramesh, K.
Ramesh, S.
author_sort Chong, Mee Yoke
building INTI Institutional Repository
collection Online Access
description Biodegradable solid polymer electrolyte (SPE) systems composed of hydroxylethyl cellulose blended with copper(II) oxide (CuO) and yttrium(III) oxide (Y2O3) nanoparticles as fillers, magnesium trifluoromethane sulfonate salt, and 1-ethyl-3-methylimidazolium trifluoromethane sulfonate ionic liquid were prepared, and the effects of the incorporation of CuO and Y2O3 nanoparticles on the performance of the SPEs for electric double-layer capacitors (EDLCs) were compared. The X-ray diffraction results reveal that the crystallinity of the SPE complex decreased upon inclusion of the Y2O3 nanoparticles compared to CuO nanoparticles; this led to a higher ionic conductivity of the Y2O3-based SPE [(3.08 ± 0.01) × 10−4 S/cm] as compared to CuO [(2.03 ± 0.01) × 10−4 S/cm]. The EDLC performances demonstrated that the cell based on CuO nanoparticles had superior performance in terms of the specific capacitance, energy, and power density compared to the Y2O3-nanoparticle-based cell. However, Y2O3-nanoparticle-based cell displayed a high cyclic retention (91.32%) compared to the CuO-nanoparticle-based cell (80.46%) after 3000 charge–discharge cycles.
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spelling intimal-6812017-02-16T09:27:24Z http://eprints.intimal.edu.my/681/ Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors Chong, Mee Yoke Arshid, Numan Chiam, Wen Liew Ramesh, K. Ramesh, S. QC Physics Biodegradable solid polymer electrolyte (SPE) systems composed of hydroxylethyl cellulose blended with copper(II) oxide (CuO) and yttrium(III) oxide (Y2O3) nanoparticles as fillers, magnesium trifluoromethane sulfonate salt, and 1-ethyl-3-methylimidazolium trifluoromethane sulfonate ionic liquid were prepared, and the effects of the incorporation of CuO and Y2O3 nanoparticles on the performance of the SPEs for electric double-layer capacitors (EDLCs) were compared. The X-ray diffraction results reveal that the crystallinity of the SPE complex decreased upon inclusion of the Y2O3 nanoparticles compared to CuO nanoparticles; this led to a higher ionic conductivity of the Y2O3-based SPE [(3.08 ± 0.01) × 10−4 S/cm] as compared to CuO [(2.03 ± 0.01) × 10−4 S/cm]. The EDLC performances demonstrated that the cell based on CuO nanoparticles had superior performance in terms of the specific capacitance, energy, and power density compared to the Y2O3-nanoparticle-based cell. However, Y2O3-nanoparticle-based cell displayed a high cyclic retention (91.32%) compared to the CuO-nanoparticle-based cell (80.46%) after 3000 charge–discharge cycles. John Wiley & Sons, Inc. 2017 Article PeerReviewed Chong, Mee Yoke and Arshid, Numan and Chiam, Wen Liew and Ramesh, K. and Ramesh, S. (2017) Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors. Journal of Applied Polymer Science, 134 (13). ISSN 1097-4628 http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1097-4628 10.1002/app.44636
spellingShingle QC Physics
Chong, Mee Yoke
Arshid, Numan
Chiam, Wen Liew
Ramesh, K.
Ramesh, S.
Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
title Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
title_full Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
title_fullStr Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
title_full_unstemmed Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
title_short Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
title_sort comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors
topic QC Physics
url http://eprints.intimal.edu.my/681/
http://eprints.intimal.edu.my/681/
http://eprints.intimal.edu.my/681/