Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell

This study demonstrates the use of carbon nanotube polypyrrole (CNT/PPy) nanocomposite as a novel cathode catalyst in microbial fuel cells (MFC). The CNT/PPy nanocomposite has been prepared using a chemical oxidative method and its performance in MFC was evaluated and compared with platinum, the...

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Main Authors: Ghasemi, Mostafa, Wan Daud, Wan Ramli, Hassan, Sedky H.A., Jafary, Tahereh, Rahimnejad, Mostafa, Ahmad, Azri, Yazdi, Mohammad H.
Format: Article
Language:English
Published: Elsevier 2015
Subjects:
Online Access:http://eprints.intimal.edu.my/232/
http://eprints.intimal.edu.my/232/1/Carbon%20nanotube_polypyrrole%20nanocomposite%20as%20a%20novel.pdf
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author Ghasemi, Mostafa
Wan Daud, Wan Ramli
Hassan, Sedky H.A.
Jafary, Tahereh
Rahimnejad, Mostafa
Ahmad, Azri
Yazdi, Mohammad H.
author_facet Ghasemi, Mostafa
Wan Daud, Wan Ramli
Hassan, Sedky H.A.
Jafary, Tahereh
Rahimnejad, Mostafa
Ahmad, Azri
Yazdi, Mohammad H.
author_sort Ghasemi, Mostafa
building INTI Institutional Repository
collection Online Access
description This study demonstrates the use of carbon nanotube polypyrrole (CNT/PPy) nanocomposite as a novel cathode catalyst in microbial fuel cells (MFC). The CNT/PPy nanocomposite has been prepared using a chemical oxidative method and its performance in MFC was evaluated and compared with platinum, the traditional cathode catalyst. The attachment of microorganisms on the anode was confirmed using field emission scanning electronic microscopy (FESEM) analysis. The size of ppy nanoparticles was also observed using SEM. Cyclic voltammetry (CV) studies were done to investigate the catalytic properties of CNT/PPy nanocomposite. The maximum power density and coulombic efficiency attained by the usage of CNT/PPy nanocomposite was found to be ~113 mW/m2 and 21% respectively, which is a significant comparison with the Pt catalyst, where the measured values were 122.7 mW/m2 and 24.6% respectively. The COD removal of both systems was found to be more than 80%. The results indicate that CNT/PPy nanocomposite could be used as a possible lower cost alternative than Pt catalyst in MFC.
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spelling intimal-2322016-09-09T07:34:59Z http://eprints.intimal.edu.my/232/ Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell Ghasemi, Mostafa Wan Daud, Wan Ramli Hassan, Sedky H.A. Jafary, Tahereh Rahimnejad, Mostafa Ahmad, Azri Yazdi, Mohammad H. TP Chemical technology This study demonstrates the use of carbon nanotube polypyrrole (CNT/PPy) nanocomposite as a novel cathode catalyst in microbial fuel cells (MFC). The CNT/PPy nanocomposite has been prepared using a chemical oxidative method and its performance in MFC was evaluated and compared with platinum, the traditional cathode catalyst. The attachment of microorganisms on the anode was confirmed using field emission scanning electronic microscopy (FESEM) analysis. The size of ppy nanoparticles was also observed using SEM. Cyclic voltammetry (CV) studies were done to investigate the catalytic properties of CNT/PPy nanocomposite. The maximum power density and coulombic efficiency attained by the usage of CNT/PPy nanocomposite was found to be ~113 mW/m2 and 21% respectively, which is a significant comparison with the Pt catalyst, where the measured values were 122.7 mW/m2 and 24.6% respectively. The COD removal of both systems was found to be more than 80%. The results indicate that CNT/PPy nanocomposite could be used as a possible lower cost alternative than Pt catalyst in MFC. Elsevier 2015 Article PeerReviewed text en http://eprints.intimal.edu.my/232/1/Carbon%20nanotube_polypyrrole%20nanocomposite%20as%20a%20novel.pdf Ghasemi, Mostafa and Wan Daud, Wan Ramli and Hassan, Sedky H.A. and Jafary, Tahereh and Rahimnejad, Mostafa and Ahmad, Azri and Yazdi, Mohammad H. (2015) Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell. International Journal of Hydrogen Energy. pp. 4872-4878. ISSN 0360-3199 10.1016/j.ijhydene.2015.09.011
spellingShingle TP Chemical technology
Ghasemi, Mostafa
Wan Daud, Wan Ramli
Hassan, Sedky H.A.
Jafary, Tahereh
Rahimnejad, Mostafa
Ahmad, Azri
Yazdi, Mohammad H.
Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
title Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
title_full Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
title_fullStr Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
title_full_unstemmed Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
title_short Carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for Pt in microbial fuel cell
title_sort carbon nanotube/polypyrrole nanocomposite as a novel cathode catalyst and proper alternative for pt in microbial fuel cell
topic TP Chemical technology
url http://eprints.intimal.edu.my/232/
http://eprints.intimal.edu.my/232/
http://eprints.intimal.edu.my/232/1/Carbon%20nanotube_polypyrrole%20nanocomposite%20as%20a%20novel.pdf