Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives

To reduce the consumption of synthetic polymers, researchers have studied the use of carbohydrates, lipids, proteins and composites to generate biodegradable plastic. In this study, degradable plastic from sago starch modified with prepolymer polyurethane synthesized from diphenylmethylene dii...

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Main Authors: Rozanna, Dewi, Zulnazri, B., Novi Sylvia, C., Iqbal Kamar, D., Medyan Riza, E.
Format: Article
Language:English
English
Published: INTI International University 2023
Subjects:
Online Access:http://eprints.intimal.edu.my/1876/
http://eprints.intimal.edu.my/1876/1/joit2023_16r.pdf
http://eprints.intimal.edu.my/1876/2/324
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author Rozanna, Dewi
Zulnazri, B.
Novi Sylvia, C.
Iqbal Kamar, D.
Medyan Riza, E.
author_facet Rozanna, Dewi
Zulnazri, B.
Novi Sylvia, C.
Iqbal Kamar, D.
Medyan Riza, E.
author_sort Rozanna, Dewi
building INTI Institutional Repository
collection Online Access
description To reduce the consumption of synthetic polymers, researchers have studied the use of carbohydrates, lipids, proteins and composites to generate biodegradable plastic. In this study, degradable plastic from sago starch modified with prepolymer polyurethane synthesized from diphenylmethylene diisocyanates and polyol with the addition of chitosan as additive and polypropylene or polyethylene as matrix was produced. The research method conducted were consisting of several stages, preparation of thermoplastic starch, blending thermoplastic starch with polypropylene or polyethylene, synthesis of degradable plastic and irradiation process. Thermoplastic starch was characterized using Scanning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX) and X-Ray Diffraction (XRD). SEM-EDX to study surface morphology, meanwhile XRD to determine the crystallinity of thermoplastic starch. The SEM analysis of 5000x magnification showed the presence of many material elements in the thermoplastic starch matrix that are visible on the entire surface of the plastic. The results of EDX analysis revealed the presence of chemical elements such as carbon, oxygen, magnesium, calcium, titanium, palladium, gold, and carbon dioxide. These elements came from the thermoplastic starch made from sago which contains magnesium (iron), calcium and the main additive CaCO3. From the XRD analysis results, it can be shown that thermoplastic starch was amorphous and crystalline. XRD analysis of thermoplastic starch has a low crystallinity value at 26.85140 .
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language English
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spelling intimal-18762025-07-21T08:53:08Z http://eprints.intimal.edu.my/1876/ Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives Rozanna, Dewi Zulnazri, B. Novi Sylvia, C. Iqbal Kamar, D. Medyan Riza, E. T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology To reduce the consumption of synthetic polymers, researchers have studied the use of carbohydrates, lipids, proteins and composites to generate biodegradable plastic. In this study, degradable plastic from sago starch modified with prepolymer polyurethane synthesized from diphenylmethylene diisocyanates and polyol with the addition of chitosan as additive and polypropylene or polyethylene as matrix was produced. The research method conducted were consisting of several stages, preparation of thermoplastic starch, blending thermoplastic starch with polypropylene or polyethylene, synthesis of degradable plastic and irradiation process. Thermoplastic starch was characterized using Scanning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX) and X-Ray Diffraction (XRD). SEM-EDX to study surface morphology, meanwhile XRD to determine the crystallinity of thermoplastic starch. The SEM analysis of 5000x magnification showed the presence of many material elements in the thermoplastic starch matrix that are visible on the entire surface of the plastic. The results of EDX analysis revealed the presence of chemical elements such as carbon, oxygen, magnesium, calcium, titanium, palladium, gold, and carbon dioxide. These elements came from the thermoplastic starch made from sago which contains magnesium (iron), calcium and the main additive CaCO3. From the XRD analysis results, it can be shown that thermoplastic starch was amorphous and crystalline. XRD analysis of thermoplastic starch has a low crystallinity value at 26.85140 . INTI International University 2023-12 Article PeerReviewed text en cc_by_4 http://eprints.intimal.edu.my/1876/1/joit2023_16r.pdf text en cc_by_4 http://eprints.intimal.edu.my/1876/2/324 Rozanna, Dewi and Zulnazri, B. and Novi Sylvia, C. and Iqbal Kamar, D. and Medyan Riza, E. (2023) Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives. Journal of Innovation and Technology, 2023 (16). pp. 1-7. ISSN 2805-5179 http://ipublishing.intimal.edu.my/joint.html
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Rozanna, Dewi
Zulnazri, B.
Novi Sylvia, C.
Iqbal Kamar, D.
Medyan Riza, E.
Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives
title Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives
title_full Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives
title_fullStr Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives
title_full_unstemmed Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives
title_short Morphology and Crystallinity Study of Sago Starch-Based Degradable Plastic with Chitosan and Calcium Carbonate as Additives
title_sort morphology and crystallinity study of sago starch-based degradable plastic with chitosan and calcium carbonate as additives
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
url http://eprints.intimal.edu.my/1876/
http://eprints.intimal.edu.my/1876/
http://eprints.intimal.edu.my/1876/1/joit2023_16r.pdf
http://eprints.intimal.edu.my/1876/2/324