The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol
In the present work, a novel polymer composite electrolytes (PCEs) based on poly(vinyl alcohol) (PVA): ammonium thiocyanate (NH4SCN): Cd(II)-complex plasticized with glycerol (Gly) are prepared by solution cast technique. The film structure was examined by XRD and FTIR routes. The utmost ambient tem...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English English |
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MDPI
2020
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| Online Access: | http://irep.iium.edu.my/82348/ http://irep.iium.edu.my/82348/1/82348_The%20Study%20of%20EDLC%20Device%20with%20High%20Electrochemical-ft.pdf http://irep.iium.edu.my/82348/7/82348%20The%20study%20of%20EDLC%20device%20with%20high%20electrochemical%20SCOPUS.pdf |
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| author | Brza, Mohamad A. Aziz, Shujahadeen Anuar, Hazleen Dannoun, Elham M.A Ali, Fathilah Abdulwahid, Rebar T. Al-Zangana, Shakhawan Kadir, Mohd F. Z. |
| author_facet | Brza, Mohamad A. Aziz, Shujahadeen Anuar, Hazleen Dannoun, Elham M.A Ali, Fathilah Abdulwahid, Rebar T. Al-Zangana, Shakhawan Kadir, Mohd F. Z. |
| author_sort | Brza, Mohamad A. |
| building | IIUM Repository |
| collection | Online Access |
| description | In the present work, a novel polymer composite electrolytes (PCEs) based on poly(vinyl alcohol) (PVA): ammonium thiocyanate (NH4SCN): Cd(II)-complex plasticized with glycerol (Gly) are prepared by solution cast technique. The film structure was examined by XRD and FTIR routes. The utmost ambient temperature DC ionic conductivity (σDC) of 2.01 × 10−3 S cm−1 is achieved. The film morphology was studied by field emission scanning electron microscopy (FESEM). The trend of σDC is further confirmed with investigation of dielectric properties. Transference numbers of ions (tion) and electrons (tel) are specified to be 0.96 and 0.04, respectively. Linear sweep voltammetry (LSV) displayed that the PCE potential window is 2.1 V. The desired mixture of activated carbon (AC) and carbon black was used to fabricate the electrodes of the EDLC. Cyclic voltammetry (CV) was carried out by sandwiching the PCEs between two carbon-based electrodes, and it revealed an almost rectangular shape. The EDLC exhibited specific capacitance, energy density, and equivalent series resistance with average of 160.07F/g, 18.01Wh/kg, and 51.05Ω, respectively, within 450 cycles. The EDLC demonstrated the initial power density as 4.065 × 103 W/Kg. |
| first_indexed | 2025-11-14T17:54:14Z |
| format | Article |
| id | iium-82348 |
| institution | International Islamic University Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-14T17:54:14Z |
| publishDate | 2020 |
| publisher | MDPI |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | iium-823482020-11-24T08:31:50Z http://irep.iium.edu.my/82348/ The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol Brza, Mohamad A. Aziz, Shujahadeen Anuar, Hazleen Dannoun, Elham M.A Ali, Fathilah Abdulwahid, Rebar T. Al-Zangana, Shakhawan Kadir, Mohd F. Z. TP155 Chemical engineering In the present work, a novel polymer composite electrolytes (PCEs) based on poly(vinyl alcohol) (PVA): ammonium thiocyanate (NH4SCN): Cd(II)-complex plasticized with glycerol (Gly) are prepared by solution cast technique. The film structure was examined by XRD and FTIR routes. The utmost ambient temperature DC ionic conductivity (σDC) of 2.01 × 10−3 S cm−1 is achieved. The film morphology was studied by field emission scanning electron microscopy (FESEM). The trend of σDC is further confirmed with investigation of dielectric properties. Transference numbers of ions (tion) and electrons (tel) are specified to be 0.96 and 0.04, respectively. Linear sweep voltammetry (LSV) displayed that the PCE potential window is 2.1 V. The desired mixture of activated carbon (AC) and carbon black was used to fabricate the electrodes of the EDLC. Cyclic voltammetry (CV) was carried out by sandwiching the PCEs between two carbon-based electrodes, and it revealed an almost rectangular shape. The EDLC exhibited specific capacitance, energy density, and equivalent series resistance with average of 160.07F/g, 18.01Wh/kg, and 51.05Ω, respectively, within 450 cycles. The EDLC demonstrated the initial power density as 4.065 × 103 W/Kg. MDPI 2020-08-23 Article PeerReviewed application/pdf en http://irep.iium.edu.my/82348/1/82348_The%20Study%20of%20EDLC%20Device%20with%20High%20Electrochemical-ft.pdf application/pdf en http://irep.iium.edu.my/82348/7/82348%20The%20study%20of%20EDLC%20device%20with%20high%20electrochemical%20SCOPUS.pdf Brza, Mohamad A. and Aziz, Shujahadeen and Anuar, Hazleen and Dannoun, Elham M.A and Ali, Fathilah and Abdulwahid, Rebar T. and Al-Zangana, Shakhawan and Kadir, Mohd F. Z. (2020) The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol. Polymers, 12 (9). pp. 1-25. ISSN 2073-4360 https://www.mdpi.com/2073-4360/12/9/1896 10.3390/polym12091896 |
| spellingShingle | TP155 Chemical engineering Brza, Mohamad A. Aziz, Shujahadeen Anuar, Hazleen Dannoun, Elham M.A Ali, Fathilah Abdulwahid, Rebar T. Al-Zangana, Shakhawan Kadir, Mohd F. Z. The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol |
| title | The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol |
| title_full | The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol |
| title_fullStr | The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol |
| title_full_unstemmed | The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol |
| title_short | The study of EDLC device with high electrochemical performance fabricated from proton ion conducting PVA-based polymer composite electrolytes plasticized with glycerol |
| title_sort | study of edlc device with high electrochemical performance fabricated from proton ion conducting pva-based polymer composite electrolytes plasticized with glycerol |
| topic | TP155 Chemical engineering |
| url | http://irep.iium.edu.my/82348/ http://irep.iium.edu.my/82348/ http://irep.iium.edu.my/82348/ http://irep.iium.edu.my/82348/1/82348_The%20Study%20of%20EDLC%20Device%20with%20High%20Electrochemical-ft.pdf http://irep.iium.edu.my/82348/7/82348%20The%20study%20of%20EDLC%20device%20with%20high%20electrochemical%20SCOPUS.pdf |