Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor

In this study, biodiesel was synthesized from a reaction of waste cooking oil (WCO) and methanol in the presence of catalyst which was derived from chicken bone and coconut residue in a packed bed reactor. Calcium oxide (CaO) was extracted from calcined chicken bone and nano-crystal cellulose (NCC...

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Main Authors: Zik, Nor Azyan Farrah Adila, Sulaiman, Sarina, Jamal, Parveen
Format: Article
Language:English
English
Published: Elsevier Ltd 2020
Subjects:
Online Access:http://irep.iium.edu.my/80339/
http://irep.iium.edu.my/80339/1/80339_Biodiesel%20production%20from%20waste%20cooking%20oil.pdf
http://irep.iium.edu.my/80339/2/80339_Biodiesel%20production%20from%20waste%20cooking%20oil_SCOPUS.pdf
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author Zik, Nor Azyan Farrah Adila
Sulaiman, Sarina
Jamal, Parveen
author_facet Zik, Nor Azyan Farrah Adila
Sulaiman, Sarina
Jamal, Parveen
author_sort Zik, Nor Azyan Farrah Adila
building IIUM Repository
collection Online Access
description In this study, biodiesel was synthesized from a reaction of waste cooking oil (WCO) and methanol in the presence of catalyst which was derived from chicken bone and coconut residue in a packed bed reactor. Calcium oxide (CaO) was extracted from calcined chicken bone and nano-crystal cellulose (NCC) was isolated from coconut residue by acid hydrolyzed and were supported with polyvinyl alcohol (PVA). The catalyst was analyzed using Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM), Thermogravimetric analysis (TGA) and X-ray diffraction (XRD) to study its elemental composition and surface morphology. The parameters used for the reaction were optimized by Design of Experiment (DOE) using Central Composite Design (CCD) to maximize the biodiesel yield. The maximum yield of 98.40% was obtained at optimum temperature, methanol to oil and catalyst loading of 65 �C, 6:1 and 0.5 wt%, respectively. Investigation on the kinetic of the reaction specified that the reaction followed pseudo first order reaction with k-value ranged from 0.0092 min1 to 0.0151 cm1 and Thiele modulus was less than 2. The activation energy Ea for the transesterification reaction was 45.72 kJ/mol.
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institution International Islamic University Malaysia
institution_category Local University
language English
English
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publishDate 2020
publisher Elsevier Ltd
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spelling iium-803392021-01-20T14:59:32Z http://irep.iium.edu.my/80339/ Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor Zik, Nor Azyan Farrah Adila Sulaiman, Sarina Jamal, Parveen TP155 Chemical engineering In this study, biodiesel was synthesized from a reaction of waste cooking oil (WCO) and methanol in the presence of catalyst which was derived from chicken bone and coconut residue in a packed bed reactor. Calcium oxide (CaO) was extracted from calcined chicken bone and nano-crystal cellulose (NCC) was isolated from coconut residue by acid hydrolyzed and were supported with polyvinyl alcohol (PVA). The catalyst was analyzed using Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM), Thermogravimetric analysis (TGA) and X-ray diffraction (XRD) to study its elemental composition and surface morphology. The parameters used for the reaction were optimized by Design of Experiment (DOE) using Central Composite Design (CCD) to maximize the biodiesel yield. The maximum yield of 98.40% was obtained at optimum temperature, methanol to oil and catalyst loading of 65 �C, 6:1 and 0.5 wt%, respectively. Investigation on the kinetic of the reaction specified that the reaction followed pseudo first order reaction with k-value ranged from 0.0092 min1 to 0.0151 cm1 and Thiele modulus was less than 2. The activation energy Ea for the transesterification reaction was 45.72 kJ/mol. Elsevier Ltd 2020 Article PeerReviewed application/pdf en http://irep.iium.edu.my/80339/1/80339_Biodiesel%20production%20from%20waste%20cooking%20oil.pdf application/pdf en http://irep.iium.edu.my/80339/2/80339_Biodiesel%20production%20from%20waste%20cooking%20oil_SCOPUS.pdf Zik, Nor Azyan Farrah Adila and Sulaiman, Sarina and Jamal, Parveen (2020) Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor. Renewable Energy, 155. pp. 267-277. ISSN 0960-1481 https://www.sciencedirect.com/science/article/abs/pii/S0960148120304778 https://doi.org/10.1016/j.renene.2020.03.144
spellingShingle TP155 Chemical engineering
Zik, Nor Azyan Farrah Adila
Sulaiman, Sarina
Jamal, Parveen
Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
title Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
title_full Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
title_fullStr Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
title_full_unstemmed Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
title_short Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
title_sort biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bedreactor
topic TP155 Chemical engineering
url http://irep.iium.edu.my/80339/
http://irep.iium.edu.my/80339/
http://irep.iium.edu.my/80339/
http://irep.iium.edu.my/80339/1/80339_Biodiesel%20production%20from%20waste%20cooking%20oil.pdf
http://irep.iium.edu.my/80339/2/80339_Biodiesel%20production%20from%20waste%20cooking%20oil_SCOPUS.pdf