Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model

The objectives of this FRGS project were to develop a novel model that can accurately describe the current-voltage characteristics of organic solar cells and photodiodes and to understand the effect of various device properties on the device performance, particularly the active layer’s properties. A...

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Main Author: Inche Ibrahim, Mohd Lukman
Format: Monograph
Language:English
Published: 2020
Subjects:
Online Access:http://irep.iium.edu.my/78080/
http://irep.iium.edu.my/78080/1/Full%20Report%20FRGS17-041-0607.pdf
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author Inche Ibrahim, Mohd Lukman
author_facet Inche Ibrahim, Mohd Lukman
author_sort Inche Ibrahim, Mohd Lukman
building IIUM Repository
collection Online Access
description The objectives of this FRGS project were to develop a novel model that can accurately describe the current-voltage characteristics of organic solar cells and photodiodes and to understand the effect of various device properties on the device performance, particularly the active layer’s properties. A novel model that describes the working principle of organic bulk heterojunction solar cells (or photovoltaic cells) was successfully developed and validated. Then, by using the developed model, the effect of the charge carrier mobility, injection barrier, active layer thickness, and light absorption profile were investigated. It was found that the optimum carrier mobility is about 1 x 10^(-6) m^2V^(-1)s^(-1). Concerning the injection barrier, it should not be larger than 0.1 eV in order to maximize the open-circuit voltage, and thus to maximize the achievable power conversion efficiency (PCE). Furthermore, for a low-recombination-loss organic photovoltaics (OPV) with ideal light trapping, the active layer thickness weakly influences the PCE, whereas for a high-recombination-loss OPV with ideal light trapping, the active layer thickness strongly influences the PCE. It was also found that the use of the correct light absorption profile can be important to accurately predict the current-voltage and the performance of OPVs. Finally, if an OPV has a very high carrier mobility imbalance, the light absorption should be concentrated near the electrode collecting the slower carrier type in order to maximize the PCE of the OPV. However, if an OPV has a mobility imbalance that is not very high, light absorption should be concentrated at the centre of the active layer in order to maximize the PCE of the OPV.
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institution International Islamic University Malaysia
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language English
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spelling iium-780802020-10-21T01:04:37Z http://irep.iium.edu.my/78080/ Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model Inche Ibrahim, Mohd Lukman QC Physics TK1001 Production of electric energy. Powerplants The objectives of this FRGS project were to develop a novel model that can accurately describe the current-voltage characteristics of organic solar cells and photodiodes and to understand the effect of various device properties on the device performance, particularly the active layer’s properties. A novel model that describes the working principle of organic bulk heterojunction solar cells (or photovoltaic cells) was successfully developed and validated. Then, by using the developed model, the effect of the charge carrier mobility, injection barrier, active layer thickness, and light absorption profile were investigated. It was found that the optimum carrier mobility is about 1 x 10^(-6) m^2V^(-1)s^(-1). Concerning the injection barrier, it should not be larger than 0.1 eV in order to maximize the open-circuit voltage, and thus to maximize the achievable power conversion efficiency (PCE). Furthermore, for a low-recombination-loss organic photovoltaics (OPV) with ideal light trapping, the active layer thickness weakly influences the PCE, whereas for a high-recombination-loss OPV with ideal light trapping, the active layer thickness strongly influences the PCE. It was also found that the use of the correct light absorption profile can be important to accurately predict the current-voltage and the performance of OPVs. Finally, if an OPV has a very high carrier mobility imbalance, the light absorption should be concentrated near the electrode collecting the slower carrier type in order to maximize the PCE of the OPV. However, if an OPV has a mobility imbalance that is not very high, light absorption should be concentrated at the centre of the active layer in order to maximize the PCE of the OPV. 2020-01-14 Monograph NonPeerReviewed application/pdf en http://irep.iium.edu.my/78080/1/Full%20Report%20FRGS17-041-0607.pdf Inche Ibrahim, Mohd Lukman (2020) Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model. Research Report. UNSPECIFIED. (Unpublished) FRGS/1/2017/STG02/UIAM/03/2
spellingShingle QC Physics
TK1001 Production of electric energy. Powerplants
Inche Ibrahim, Mohd Lukman
Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
title Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
title_full Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
title_fullStr Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
title_full_unstemmed Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
title_short Impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
title_sort impacts of the photoactive layer's properties on the performance of organic solar cells and photodiodes based on a novel model
topic QC Physics
TK1001 Production of electric energy. Powerplants
url http://irep.iium.edu.my/78080/
http://irep.iium.edu.my/78080/
http://irep.iium.edu.my/78080/1/Full%20Report%20FRGS17-041-0607.pdf