Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films

KNN thin films with diverse yttrium concentration (mol % = 0, 0.1, 0.3, 0.5, 0.7 and 0.9) were fabricated using sol-gel spin coating technique. Doped KNN revealed that Y3+ was successfully doped into the ABO3 perovskite lattice without changing the phase formation of KNN. The thickness of the d...

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Main Authors: Mohd Hatta, Maziati Akmal, Abd Rashid, Mohd Warikh M., Azlan, Umar Al Amani, Azmi,, Nurul Azuwa, Azam, Mohd Asyadi, Moriga, Toshihiro
Format: Article
Language:English
English
Published: Universidade Federal de Sao Carlos 2016
Subjects:
Online Access:http://irep.iium.edu.my/67746/
http://irep.iium.edu.my/67746/1/Materials%20Research.pdf
http://irep.iium.edu.my/67746/8/67746%20Influence%20of%20yttrium%20dopant%20on%20the%20structure%20and%20electrical%20conductivity%20of%20potassium%20%20SCOPUS.pdf
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author Mohd Hatta, Maziati Akmal
Abd Rashid, Mohd Warikh M.
Azlan, Umar Al Amani
Azmi,, Nurul Azuwa
Azam, Mohd Asyadi
Moriga, Toshihiro
author_facet Mohd Hatta, Maziati Akmal
Abd Rashid, Mohd Warikh M.
Azlan, Umar Al Amani
Azmi,, Nurul Azuwa
Azam, Mohd Asyadi
Moriga, Toshihiro
author_sort Mohd Hatta, Maziati Akmal
building IIUM Repository
collection Online Access
description KNN thin films with diverse yttrium concentration (mol % = 0, 0.1, 0.3, 0.5, 0.7 and 0.9) were fabricated using sol-gel spin coating technique. Doped KNN revealed that Y3+ was successfully doped into the ABO3 perovskite lattice without changing the phase formation of KNN. The thickness of the deposited layer of KNN produced with increasing dopant concentration was determined to be 200 nm with dense and well-defined grains. Afterwards, the vibrational bonding and conductivity of KNN films with diverse yttrium concentration were identified according to the charge compensation mechanism. At high dopant concentration of > 0.5 mol %, O-Nb-O bonding was asymmetric and became distorted due to B-site occupancy by yttrium dopant. Further investigation revealed that charge compensation mechanism was shifted by increasing doping concentration. As a result, yttrium-doped KNN became semi-conductive at low yttrium concentration. Meanwhile, at high concentration, yttrium-doped KNN became an insulator and underwent ionic compensation
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language English
English
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publishDate 2016
publisher Universidade Federal de Sao Carlos
recordtype eprints
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spelling iium-677462019-07-12T03:37:05Z http://irep.iium.edu.my/67746/ Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films Mohd Hatta, Maziati Akmal Abd Rashid, Mohd Warikh M. Azlan, Umar Al Amani Azmi,, Nurul Azuwa Azam, Mohd Asyadi Moriga, Toshihiro Q Science (General) KNN thin films with diverse yttrium concentration (mol % = 0, 0.1, 0.3, 0.5, 0.7 and 0.9) were fabricated using sol-gel spin coating technique. Doped KNN revealed that Y3+ was successfully doped into the ABO3 perovskite lattice without changing the phase formation of KNN. The thickness of the deposited layer of KNN produced with increasing dopant concentration was determined to be 200 nm with dense and well-defined grains. Afterwards, the vibrational bonding and conductivity of KNN films with diverse yttrium concentration were identified according to the charge compensation mechanism. At high dopant concentration of > 0.5 mol %, O-Nb-O bonding was asymmetric and became distorted due to B-site occupancy by yttrium dopant. Further investigation revealed that charge compensation mechanism was shifted by increasing doping concentration. As a result, yttrium-doped KNN became semi-conductive at low yttrium concentration. Meanwhile, at high concentration, yttrium-doped KNN became an insulator and underwent ionic compensation Universidade Federal de Sao Carlos 2016-11 Article PeerReviewed application/pdf en http://irep.iium.edu.my/67746/1/Materials%20Research.pdf application/pdf en http://irep.iium.edu.my/67746/8/67746%20Influence%20of%20yttrium%20dopant%20on%20the%20structure%20and%20electrical%20conductivity%20of%20potassium%20%20SCOPUS.pdf Mohd Hatta, Maziati Akmal and Abd Rashid, Mohd Warikh M. and Azlan, Umar Al Amani and Azmi,, Nurul Azuwa and Azam, Mohd Asyadi and Moriga, Toshihiro (2016) Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films. Materials Research, 19 (6 (November/December)). pp. 1417-1422. ISSN 1516-1439 E-ISSN 1980-5373 http://www.scielo.br/pdf/mr/v19n6/1516-1439-mr-1980-5373-MR-2016-0076.pdf 10.1590/1980-5373-mr-2016-0076
spellingShingle Q Science (General)
Mohd Hatta, Maziati Akmal
Abd Rashid, Mohd Warikh M.
Azlan, Umar Al Amani
Azmi,, Nurul Azuwa
Azam, Mohd Asyadi
Moriga, Toshihiro
Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
title Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
title_full Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
title_fullStr Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
title_full_unstemmed Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
title_short Influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
title_sort influence of yttrium dopant on the structure and electrical conductivity of potassium sodium niobate thin films
topic Q Science (General)
url http://irep.iium.edu.my/67746/
http://irep.iium.edu.my/67746/
http://irep.iium.edu.my/67746/
http://irep.iium.edu.my/67746/1/Materials%20Research.pdf
http://irep.iium.edu.my/67746/8/67746%20Influence%20of%20yttrium%20dopant%20on%20the%20structure%20and%20electrical%20conductivity%20of%20potassium%20%20SCOPUS.pdf