Tuning the accessibility and activity of Au25(SR)18 nanocluster catalysts through ligand engineering

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Tuning the accessibility and activity of Au25(SR)18 nanocluster catalysts through ligand engineering

In this work, the effects of thiolate ligands (-SR, e.g., chain length and functional moiety) on the accessibility and catalytic activity of thiolate-protected gold nanoclusters (e.g., Au25(SR)18) for 4-nitrophenol hydrogenation is reported. The data suggest that Au25(SR)18 bearing a shorter alkyl...

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Bibliographic Details
Main Authors:	Li, Jingguo, Nasaruddin, Ricca Rahman, Feng, Yan, Yang, Jun, Yan, Ning, Xie, Jianping
Format:	Article
Language:	English English
Published:	WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 2016
Subjects:	QD Chemistry TP155 Chemical engineering
Online Access:	http://irep.iium.edu.my/66300/ http://irep.iium.edu.my/66300/1/2016%20-%20tuning%20cat%20phd%20-%20chem%20eur%20j.pdf http://irep.iium.edu.my/66300/2/2016%20-%20tuning%20cat%20phd%20-%20chem%20eur%20j%20-%20SD.pdf

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