Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydroge...
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| Format: | Proceeding Paper |
| Language: | English English |
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Trans Tech. Publications
2017
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| Online Access: | http://irep.iium.edu.my/56699/ http://irep.iium.edu.my/56699/13/56699_Effect%20of%20metals%20compatibility%20on%20fluorine-doped.pdf http://irep.iium.edu.my/56699/24/56699-Effect%20of%20metals%20compatibility%20on%20fluorine-doped%20tin-SCOPUS.pdf |
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| author | Samad, Wan Zurina Wan Isahak, Wan Nor Roslam Hamzah, Noraini Yarmo, Mohd Ambar Yusop, Muhammad Rahimi |
| author_facet | Samad, Wan Zurina Wan Isahak, Wan Nor Roslam Hamzah, Noraini Yarmo, Mohd Ambar Yusop, Muhammad Rahimi |
| author_sort | Samad, Wan Zurina |
| building | IIUM Repository |
| collection | Online Access |
| description | The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established |
| first_indexed | 2025-11-14T16:42:52Z |
| format | Proceeding Paper |
| id | iium-56699 |
| institution | International Islamic University Malaysia |
| institution_category | Local University |
| language | English English |
| last_indexed | 2025-11-14T16:42:52Z |
| publishDate | 2017 |
| publisher | Trans Tech. Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | iium-566992018-03-15T09:33:24Z http://irep.iium.edu.my/56699/ Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol Samad, Wan Zurina Wan Isahak, Wan Nor Roslam Hamzah, Noraini Yarmo, Mohd Ambar Yusop, Muhammad Rahimi Q Science (General) The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established Trans Tech. Publications 2017-03 Proceeding Paper PeerReviewed application/pdf en http://irep.iium.edu.my/56699/13/56699_Effect%20of%20metals%20compatibility%20on%20fluorine-doped.pdf application/pdf en http://irep.iium.edu.my/56699/24/56699-Effect%20of%20metals%20compatibility%20on%20fluorine-doped%20tin-SCOPUS.pdf Samad, Wan Zurina and Wan Isahak, Wan Nor Roslam and Hamzah, Noraini and Yarmo, Mohd Ambar and Yusop, Muhammad Rahimi (2017) Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol. In: International Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016, 17th-18th August, 2016, Dorsett Hotel, Putrajaya. https://www.scientific.net/MSF.888.496 10.4028/www.scientific.net/MSF.888.496 |
| spellingShingle | Q Science (General) Samad, Wan Zurina Wan Isahak, Wan Nor Roslam Hamzah, Noraini Yarmo, Mohd Ambar Yusop, Muhammad Rahimi Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol |
| title | Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol |
| title_full | Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol |
| title_fullStr | Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol |
| title_full_unstemmed | Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol |
| title_short | Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol |
| title_sort | effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol |
| topic | Q Science (General) |
| url | http://irep.iium.edu.my/56699/ http://irep.iium.edu.my/56699/ http://irep.iium.edu.my/56699/ http://irep.iium.edu.my/56699/13/56699_Effect%20of%20metals%20compatibility%20on%20fluorine-doped.pdf http://irep.iium.edu.my/56699/24/56699-Effect%20of%20metals%20compatibility%20on%20fluorine-doped%20tin-SCOPUS.pdf |