Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose

Biodegradable polymers have been extensively studied in order to substitute the synthetic polymers since they are non-biodegradable which is harmful to environment. Polycaprolactone (PCL) could be a good candidate to substitute synthetic polymer since it can be slowly degraded by microbes. PCL was s...

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Main Authors: Jimat, Dzun Noraini, Sulaiman, Sarina, Ariffin, Faridah
Format: Proceeding Paper
Language:English
Published: Kulliyah of Engineering, International Islamic University Malaysia 2016
Subjects:
Online Access:http://irep.iium.edu.my/54852/
http://irep.iium.edu.my/54852/15/54852.pdf
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author Jimat, Dzun Noraini
Sulaiman, Sarina
Ariffin, Faridah
author_facet Jimat, Dzun Noraini
Sulaiman, Sarina
Ariffin, Faridah
author_sort Jimat, Dzun Noraini
building IIUM Repository
collection Online Access
description Biodegradable polymers have been extensively studied in order to substitute the synthetic polymers since they are non-biodegradable which is harmful to environment. Polycaprolactone (PCL) could be a good candidate to substitute synthetic polymer since it can be slowly degraded by microbes. PCL was synthesized by ring-opening polymerization of -caprolactone with stannous octoate as catalyst. To improve the mechanical strength of PCL, it was reinforced with microfibrillated cellulose (MFC) and starch acts as filler. MFC was extracted from sugarcane bagasse (SCB) through chemo-mechanical treatments. Characterizations of the PCL-starch composite reinforced with SCB-MFC with respect to its morphology and structural changes were evaluated. In this study, amount of tapioca starch was fixed at 40%. Meanwhile, the composition of SCB-MFC and PCL were varied 50% to 58% and 2% to 10% respectively. Initial observation from microscopy images showed that there were significant changes of morphology of PCL after adding starch and SCB-MFC. The surface of biocomposite PCL-starch-SCB-MFC was quite uniform and smooth with less 5% of SCB-MFC. However, fine aggregates was observed on the sample with 10% of MFC-SCB due to the presence of sugarcane bagasse microfibril cellulose.
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format Proceeding Paper
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institution International Islamic University Malaysia
institution_category Local University
language English
last_indexed 2025-11-14T16:37:53Z
publishDate 2016
publisher Kulliyah of Engineering, International Islamic University Malaysia
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spelling iium-548522017-02-21T07:48:35Z http://irep.iium.edu.my/54852/ Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose Jimat, Dzun Noraini Sulaiman, Sarina Ariffin, Faridah TA401 Materials of engineering and construction Biodegradable polymers have been extensively studied in order to substitute the synthetic polymers since they are non-biodegradable which is harmful to environment. Polycaprolactone (PCL) could be a good candidate to substitute synthetic polymer since it can be slowly degraded by microbes. PCL was synthesized by ring-opening polymerization of -caprolactone with stannous octoate as catalyst. To improve the mechanical strength of PCL, it was reinforced with microfibrillated cellulose (MFC) and starch acts as filler. MFC was extracted from sugarcane bagasse (SCB) through chemo-mechanical treatments. Characterizations of the PCL-starch composite reinforced with SCB-MFC with respect to its morphology and structural changes were evaluated. In this study, amount of tapioca starch was fixed at 40%. Meanwhile, the composition of SCB-MFC and PCL were varied 50% to 58% and 2% to 10% respectively. Initial observation from microscopy images showed that there were significant changes of morphology of PCL after adding starch and SCB-MFC. The surface of biocomposite PCL-starch-SCB-MFC was quite uniform and smooth with less 5% of SCB-MFC. However, fine aggregates was observed on the sample with 10% of MFC-SCB due to the presence of sugarcane bagasse microfibril cellulose. Kulliyah of Engineering, International Islamic University Malaysia 2016 Proceeding Paper PeerReviewed application/pdf en http://irep.iium.edu.my/54852/15/54852.pdf Jimat, Dzun Noraini and Sulaiman, Sarina and Ariffin, Faridah (2016) Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose. In: 4th International Conference on Biotechnology Engineering 2016 (ICBioE 2016), 25th-27th July 2016, Kuala Lumpur. http://www.iium.edu.my/icbioe/2016/
spellingShingle TA401 Materials of engineering and construction
Jimat, Dzun Noraini
Sulaiman, Sarina
Ariffin, Faridah
Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
title Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
title_full Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
title_fullStr Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
title_full_unstemmed Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
title_short Characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
title_sort characterization of biodegradable composite based on polycaprolactone/starch reinforced with sugarcane bagasse microfibrillated cellulose
topic TA401 Materials of engineering and construction
url http://irep.iium.edu.my/54852/
http://irep.iium.edu.my/54852/
http://irep.iium.edu.my/54852/15/54852.pdf