A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel

Recent X-ray crystal structures of the two-pore domain (K2P) family of potassium channels have revealed a unique structural architecture at the point where the cytoplasmic bundle-crossing gate is found in most other tetrameric K+ channels. However, despite the apparently open nature of the inner por...

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Main Authors: Aryal, Prafulla, Abd Wahab, Firdaus, Bucci, Giovanna, Sansom, Mark, Stephen, Tucker
Format: Article
Language:English
English
Published: Nature Publishing Group 2014
Subjects:
Online Access:http://irep.iium.edu.my/47584/
http://irep.iium.edu.my/47584/1/47584.pdf
http://irep.iium.edu.my/47584/4/47584_A%20hydrophobic%20barrier%20deep_SCOPUS.pdf
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author Aryal, Prafulla
Abd Wahab, Firdaus
Bucci, Giovanna
Sansom, Mark
Stephen, Tucker
author_facet Aryal, Prafulla
Abd Wahab, Firdaus
Bucci, Giovanna
Sansom, Mark
Stephen, Tucker
author_sort Aryal, Prafulla
building IIUM Repository
collection Online Access
description Recent X-ray crystal structures of the two-pore domain (K2P) family of potassium channels have revealed a unique structural architecture at the point where the cytoplasmic bundle-crossing gate is found in most other tetrameric K+ channels. However, despite the apparently open nature of the inner pore in the ​TWIK-1 ( K2P1/​KCNK1) crystal structure, the reasons underlying its low levels of functional activity remain unclear. In this study, we use a combination of molecular dynamics simulations and functional validation to demonstrate that ​TWIK-1 possesses a hydrophobic barrier deep within the inner pore, and that stochastic dewetting of this hydrophobic constriction acts as a major barrier to ion conduction. These results not only provide an important insight into the mechanisms which control ​TWIK-1 channel activity, but also have important implications for our understanding of how ion permeation may be controlled in similar ion channels and pores.
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spelling iium-475842018-01-09T08:49:47Z http://irep.iium.edu.my/47584/ A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel Aryal, Prafulla Abd Wahab, Firdaus Bucci, Giovanna Sansom, Mark Stephen, Tucker Q Science (General) RM Therapeutics. Pharmacology Recent X-ray crystal structures of the two-pore domain (K2P) family of potassium channels have revealed a unique structural architecture at the point where the cytoplasmic bundle-crossing gate is found in most other tetrameric K+ channels. However, despite the apparently open nature of the inner pore in the ​TWIK-1 ( K2P1/​KCNK1) crystal structure, the reasons underlying its low levels of functional activity remain unclear. In this study, we use a combination of molecular dynamics simulations and functional validation to demonstrate that ​TWIK-1 possesses a hydrophobic barrier deep within the inner pore, and that stochastic dewetting of this hydrophobic constriction acts as a major barrier to ion conduction. These results not only provide an important insight into the mechanisms which control ​TWIK-1 channel activity, but also have important implications for our understanding of how ion permeation may be controlled in similar ion channels and pores. Nature Publishing Group 2014-07-08 Article PeerReviewed application/pdf en http://irep.iium.edu.my/47584/1/47584.pdf application/pdf en http://irep.iium.edu.my/47584/4/47584_A%20hydrophobic%20barrier%20deep_SCOPUS.pdf Aryal, Prafulla and Abd Wahab, Firdaus and Bucci, Giovanna and Sansom, Mark and Stephen, Tucker (2014) A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel. Nature Communications, 5 (4377). pp. 1-9. ISSN 2041-1723 http://www.nature.com/ncomms/2014/140708/ncomms5377/full/ncomms5377.html 10.1038/ncomms5377
spellingShingle Q Science (General)
RM Therapeutics. Pharmacology
Aryal, Prafulla
Abd Wahab, Firdaus
Bucci, Giovanna
Sansom, Mark
Stephen, Tucker
A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel
title A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel
title_full A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel
title_fullStr A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel
title_full_unstemmed A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel
title_short A hydrophobic barrier deep within the inner pore of the ​TWIK-1 K2P potassium channel
title_sort hydrophobic barrier deep within the inner pore of the ​twik-1 k2p potassium channel
topic Q Science (General)
RM Therapeutics. Pharmacology
url http://irep.iium.edu.my/47584/
http://irep.iium.edu.my/47584/
http://irep.iium.edu.my/47584/
http://irep.iium.edu.my/47584/1/47584.pdf
http://irep.iium.edu.my/47584/4/47584_A%20hydrophobic%20barrier%20deep_SCOPUS.pdf