A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis

In this investigation, the potential of powdered activated carbon (PAC) derived from empty fruit bunch (EFB) precursor through pyrolysis method for chemical oxygen demand (COD) adsorption from biotreated palm oil mill effluent (POME) was extensively studied. The PAC was prepared and characteriz...

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Main Authors: Amosa, Mutiu K., Jami, Mohammed Saedi, Al-Khatib, Ma'an Fahmi Rashid, Jimat, Dzun Noraini, Muyibi, Suleyman Aremu
Format: Article
Language:English
English
Published: Springer Netherlands 2015
Subjects:
Online Access:http://irep.iium.edu.my/47331/
http://irep.iium.edu.my/47331/4/Final_Publication_witn_page_number.pdf
http://irep.iium.edu.my/47331/7/47331_A%20two-step%20optimization%20and%20statistical%20analysis%20of%20COD_Scopus.pdf
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author Amosa, Mutiu K.
Jami, Mohammed Saedi
Al-Khatib, Ma'an Fahmi Rashid
Jimat, Dzun Noraini
Muyibi, Suleyman Aremu
author_facet Amosa, Mutiu K.
Jami, Mohammed Saedi
Al-Khatib, Ma'an Fahmi Rashid
Jimat, Dzun Noraini
Muyibi, Suleyman Aremu
author_sort Amosa, Mutiu K.
building IIUM Repository
collection Online Access
description In this investigation, the potential of powdered activated carbon (PAC) derived from empty fruit bunch (EFB) precursor through pyrolysis method for chemical oxygen demand (COD) adsorption from biotreated palm oil mill effluent (POME) was extensively studied. The PAC was prepared and characterized using scanning electron microscope (SEM), Fourier transform infrared (FTIR) spectroscopy and Brunauer–Emmett–Teller. The SEM microphotographs showed opened micropores existing in the PAC structure with a surface area of 886.2 m 2 /g. The FTIR spectra revealed the three major peaks exhibited by the surface of the activated carbon at exactly wavenumbers of 1737.61, 1365.10 and 1216.91 cm -1 . This suggests the presence of some functional groups which can potentially enhance positive interactions between the adsorbent and the adsorbate.Design-Expert � software (version 7.0.0) was employed for the statistical experimental design of a twostep optimization: factorial and response surface methodology. Maximum COD reduction of 84 % (227 ppm residual) was achieved from an initial concentration of 1387 ppm. This study being the first optimization process with the utility of EFB-based PAC in the treatment of the high-strength multicomponent biotreated POME; hence, the results could serve as requisite data for upscaling and/or future investigations in the utility of the precursor as a viable adsorbent.
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language English
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publishDate 2015
publisher Springer Netherlands
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spelling iium-473312024-05-02T07:46:26Z http://irep.iium.edu.my/47331/ A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis Amosa, Mutiu K. Jami, Mohammed Saedi Al-Khatib, Ma'an Fahmi Rashid Jimat, Dzun Noraini Muyibi, Suleyman Aremu TP155 Chemical engineering In this investigation, the potential of powdered activated carbon (PAC) derived from empty fruit bunch (EFB) precursor through pyrolysis method for chemical oxygen demand (COD) adsorption from biotreated palm oil mill effluent (POME) was extensively studied. The PAC was prepared and characterized using scanning electron microscope (SEM), Fourier transform infrared (FTIR) spectroscopy and Brunauer–Emmett–Teller. The SEM microphotographs showed opened micropores existing in the PAC structure with a surface area of 886.2 m 2 /g. The FTIR spectra revealed the three major peaks exhibited by the surface of the activated carbon at exactly wavenumbers of 1737.61, 1365.10 and 1216.91 cm -1 . This suggests the presence of some functional groups which can potentially enhance positive interactions between the adsorbent and the adsorbate.Design-Expert � software (version 7.0.0) was employed for the statistical experimental design of a twostep optimization: factorial and response surface methodology. Maximum COD reduction of 84 % (227 ppm residual) was achieved from an initial concentration of 1387 ppm. This study being the first optimization process with the utility of EFB-based PAC in the treatment of the high-strength multicomponent biotreated POME; hence, the results could serve as requisite data for upscaling and/or future investigations in the utility of the precursor as a viable adsorbent. Springer Netherlands 2015-12 Article PeerReviewed application/pdf en http://irep.iium.edu.my/47331/4/Final_Publication_witn_page_number.pdf application/pdf en http://irep.iium.edu.my/47331/7/47331_A%20two-step%20optimization%20and%20statistical%20analysis%20of%20COD_Scopus.pdf Amosa, Mutiu K. and Jami, Mohammed Saedi and Al-Khatib, Ma'an Fahmi Rashid and Jimat, Dzun Noraini and Muyibi, Suleyman Aremu (2015) A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis. Water Quality, Exposure and Health, 7 (4). pp. 603-616. ISSN 1876-1658 http://link.springer.com/journal/12403 10.1007/s12403-015-0176-4
spellingShingle TP155 Chemical engineering
Amosa, Mutiu K.
Jami, Mohammed Saedi
Al-Khatib, Ma'an Fahmi Rashid
Jimat, Dzun Noraini
Muyibi, Suleyman Aremu
A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis
title A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis
title_full A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis
title_fullStr A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis
title_full_unstemmed A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis
title_short A two-step optimization and statistical analysis of COD reduction from biotreated POME using empty fruit bunch-based activated carbon produced from pyrolysis
title_sort two-step optimization and statistical analysis of cod reduction from biotreated pome using empty fruit bunch-based activated carbon produced from pyrolysis
topic TP155 Chemical engineering
url http://irep.iium.edu.my/47331/
http://irep.iium.edu.my/47331/
http://irep.iium.edu.my/47331/
http://irep.iium.edu.my/47331/4/Final_Publication_witn_page_number.pdf
http://irep.iium.edu.my/47331/7/47331_A%20two-step%20optimization%20and%20statistical%20analysis%20of%20COD_Scopus.pdf