Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices

Ionic conducting polymer thin films consist of poly (ethylene oxide)-chitosan blend, ammonium iodide NH4I and iodine crystal I2 were prepared by solution cast technique at room temperature. To improve the mechanical properties of the polymer thin film, chitosan (C6 H11 NO4) is added to the electro...

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Main Authors: Alaei, Iraj, Al bathi, Souad Ali Muhammad, Sopyan, Iis
Format: Article
Language:English
English
Published: Asian Research Publishing Network (ARPN) 2015
Subjects:
Online Access:http://irep.iium.edu.my/46969/
http://irep.iium.edu.my/46969/1/iraj_ARPN15.pdf
http://irep.iium.edu.my/46969/4/46969_Fabrication_and_characterization_of_poly_Scopus.pdf
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author Alaei, Iraj
Al bathi, Souad Ali Muhammad
Sopyan, Iis
author_facet Alaei, Iraj
Al bathi, Souad Ali Muhammad
Sopyan, Iis
author_sort Alaei, Iraj
building IIUM Repository
collection Online Access
description Ionic conducting polymer thin films consist of poly (ethylene oxide)-chitosan blend, ammonium iodide NH4I and iodine crystal I2 were prepared by solution cast technique at room temperature. To improve the mechanical properties of the polymer thin film, chitosan (C6 H11 NO4) is added to the electrolyte, ammonium iodide (NH4I) is added to supply charge carrier and iodine crystal (I2) added to provide redox couple. From the complex impedance plot, the bulk resistance Rb was determined and the conductivity of the thin film was calculated. The highest conductivity was observed for the polymer blend containing, 45 wt % ammonium iodide which yield at (1.18±0.7) x 10-5 S cm-1 by Impedance spectroscopy. Optical characterization of the highest conducting PEO and chitosan ionic conductor shows at the corresponding wavelength, 330 nm that the thin film has a band gap of 3.7 eV. The polymer thin films were smooth, flexible and transparent. Thin film polymers are more favourable for photo-electronic applications.
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institution International Islamic University Malaysia
institution_category Local University
language English
English
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publishDate 2015
publisher Asian Research Publishing Network (ARPN)
recordtype eprints
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spelling iium-469692016-07-17T20:35:35Z http://irep.iium.edu.my/46969/ Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices Alaei, Iraj Al bathi, Souad Ali Muhammad Sopyan, Iis TA401 Materials of engineering and construction Ionic conducting polymer thin films consist of poly (ethylene oxide)-chitosan blend, ammonium iodide NH4I and iodine crystal I2 were prepared by solution cast technique at room temperature. To improve the mechanical properties of the polymer thin film, chitosan (C6 H11 NO4) is added to the electrolyte, ammonium iodide (NH4I) is added to supply charge carrier and iodine crystal (I2) added to provide redox couple. From the complex impedance plot, the bulk resistance Rb was determined and the conductivity of the thin film was calculated. The highest conductivity was observed for the polymer blend containing, 45 wt % ammonium iodide which yield at (1.18±0.7) x 10-5 S cm-1 by Impedance spectroscopy. Optical characterization of the highest conducting PEO and chitosan ionic conductor shows at the corresponding wavelength, 330 nm that the thin film has a band gap of 3.7 eV. The polymer thin films were smooth, flexible and transparent. Thin film polymers are more favourable for photo-electronic applications. Asian Research Publishing Network (ARPN) 2015-12-01 Article PeerReviewed application/pdf en http://irep.iium.edu.my/46969/1/iraj_ARPN15.pdf application/pdf en http://irep.iium.edu.my/46969/4/46969_Fabrication_and_characterization_of_poly_Scopus.pdf Alaei, Iraj and Al bathi, Souad Ali Muhammad and Sopyan, Iis (2015) Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices. ARPN Journal of Engineering and Applied Sciences, 10 (22). pp. 17239-17241. ISSN 1819-6608 http://www.arpnjournals.org/jeas/research_papers/rp_2015/jeas_1215_3157.pdf
spellingShingle TA401 Materials of engineering and construction
Alaei, Iraj
Al bathi, Souad Ali Muhammad
Sopyan, Iis
Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
title Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
title_full Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
title_fullStr Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
title_full_unstemmed Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
title_short Fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
title_sort fabrication and characterization of poly (ethylene oxide) for photo-electronic devices
topic TA401 Materials of engineering and construction
url http://irep.iium.edu.my/46969/
http://irep.iium.edu.my/46969/
http://irep.iium.edu.my/46969/1/iraj_ARPN15.pdf
http://irep.iium.edu.my/46969/4/46969_Fabrication_and_characterization_of_poly_Scopus.pdf